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A Review of Lithium Supply and Demand and a Preliminary Investigation of a Room Temperature Method to Recycle Lithium Ion Batteries to Recover Lithium and Other Materials

机译:锂的供需回顾和室温回收锂离子电池以回收锂和其他材料的室温方法的初步研究

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Recent publications have discussed the potential for scarcity of materials needed for future engineering designs and manufacture [1,2, 3]. In the case of a recent DOE report [1], materials needed for the production of green energy technologies were deemed as those needing study.A major conclusion of these papers is that there is a need for recycling of materials that are designated as strategic or have a potential of becoming scarce. Lithium is one such material. It is critical to the battery industry, especially in compact consumer electronics (e.g. mobile phones and tablets) and in hybrid electrical and fully electrical vehicles. In this paper the role of lithium in electronics and vehicles is reviewed. Also reviewed are the reserves, projected mining capacity, and forecasted demand for lithium. Based on these three, it is predicted that there will be a shortage of lithium between 2021 and 2023 if lithium is not recycled [4].Current lithium ion battery technologies recover little if any lithium and are energy intensive since they incinerate or shred batteries after they have been cooled in liquid nitrogen. This paper showcases a preliminary experiment where a battery was discharged by immersion in brine and safely opened manually. Pristine copped and the external protection circuit were easily recovered intact. Future experiments will attempt to recover lithium, aluminium, and the electrolyte with the aim of developing a method of recycling at room temperature that recovers all valuable materials, especially lithium.
机译:最近的出版物讨论了未来工程设计和制造所需材料的稀缺性[1,2,3]。在最近的美国能源部报告[1]中,绿色能源技术生产所需的材料被认为是需要研究的材料。这些论文的主要结论是,需要回收指定为战略或战略材料。有可能变得稀缺。锂是一种这样的材料。这对于电池行业至关重要,尤其是在紧凑型消费电子产品(例如移动电话和平板电脑)以及混合动力电动和全电动汽车中。本文综述了锂在电子和车辆中的作用。还审查了储量,预计的采矿能力以及锂的预计需求。根据这三个方面,预计如果不回收锂,到2021年至2023年之间将出现锂短缺的情况[4]。当前的锂离子电池技术几乎不会回收任何锂,并且会消耗大量能源,因为它们会在焚化或破碎后破碎电池它们已在液氮中冷却。本文展示了一个初步实验,该实验通过将电池浸入盐水中进行放电并手动安全地打开。原始的铜管和外部保护电路很容易恢复原状。未来的实验将尝试回收锂,铝和电解质,目的是开发一种在室温下回收所有有价值的材料(尤其是锂)的回收方法。

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