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Study on Corrosion Resistance of N36 Zirconium Alloy in LiOH Aqueous Solution

机译:N36锆合金在LiOH水溶液中的耐蚀性研究

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Zr-Sn-Nb-Fe alloys are one of the important directions for continuous improvement of zirconium alloys for high burn-up fuel assemblies. The corrosion resistance of Zr-Sn-Nb-Fe alloys is closely related to the alloying element and water chemical condition. To better understand the effect of Sn on corrosion resistance of Zr-Sn-Nb-Fe alloy, the normal N36 (Zr-1Sn-1Nb-0.3Fe) and low-tin N36 (Zr-0.8Sn-1Nb-0.3Fe) alloy sheets were prepared and tested in static autoclave in both of 0.01 mol/L LiOH and 0.03 mol/L LiOH aqueous solution at 360 style="white-space:nowrap;">°C and 18.6 MPa. The characteristics of the microstructure and oxide film of alloys were analyzed by TEM and SEM respectively. It was shown that that the corrosion transition of the normal N36 appears earlier and the weight gain is higher than the low-tin N36 in two corrosive mediums. The cracks paralleling to the interface of oxide/metal are formed in the fracture surface of the oxide film and the micrographs at the oxide film/substrate interface appear uneven morphology. With the increasing of corrosion gain, there are more parallel cracks in oxide film and the uneven morphology at the oxide film/substrate interface is more obvious.
机译:Zr-Sn-Nb-Fe合金是持续改进用于高燃耗燃料组件的锆合金的重要方向之一。 Zr-Sn-Nb-Fe合金的耐蚀性与合金元素和水化学条件密切相关。为了更好地理解Sn对Zr-Sn-Nb-Fe合金,普通N36(Zr-1Sn-1Nb-0.3Fe)和低锡N36(Zr-0.8Sn-1Nb-0.3Fe)合金的耐蚀性的影响制备板并在静态高压釜中在360℃和18.6 MPa的0.01 mol / L LiOH和0.03 mol / L LiOH水溶液中进行测试。分别用TEM和SEM分析了合金的显微组织和氧化膜特征。结果表明,在两种腐蚀性介质中,普通N36的腐蚀转变出现得较早,其重量增加高于低锡N36。平行于氧化物/金属界面的裂纹形成在氧化物膜的断裂表面中,并且氧化物膜/基底界面处的显微照片呈现出不均匀的形态。随着腐蚀增益的增加,氧化膜中出现更多的平行裂纹,并且氧化膜/基体界面处的不均匀形貌更加明显。

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