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首页> 外文期刊>Der Pharma Chemica: journal for medicinal chemistry, pharmaceutical chemistry and computational chemistry >The new study compound structural of tree new aluminate complexes [AlCl3X] (X= NO3, CH3COO, N3) and study of antimicrobial activities
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The new study compound structural of tree new aluminate complexes [AlCl3X] (X= NO3, CH3COO, N3) and study of antimicrobial activities

机译：树状新型铝酸盐配合物[AlCl3X]（X = NO3，CH3COO，N3）的复合化合物的新研究和抗菌活性的研究

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The synthesis and characterization is reported of Tri aluminate (III) complexes of general formula Na[AlCl3 X], derived from monoanionic Ligands CL3X (X = No3, CH3COO, N3). Sodium Trichloronitratoaluminate, SCNA, Sodium Trichloroacetatoaluminate, SCAA, Sodium Trichloroazidoaluminate, SCAZA produced tri ionic aluminate complexes. They easily synthesized in a nearly quantitative yield using by direct reaction of AlCl3 with relative ligands. These compounds were characterized by IR, UV/Visible and Mass techniques. Concerning the molecular structure of the compound, the AL(III) cation (2S2,2P66) with four sp3 hybrided orbitals can form stable hero complex with two kind coordinating atoms, 3Cl , X atoms can be coordinated to the (AL) ion. The AL and Cl ,X atoms and the title ligand are disordered. Suggestion structural distortions away from the idealized C3V geometry. The antibacterial activities of synthesized compounds were studied against the four Gram-positive bacteria: Streptococcus pyogenes, Streptococcus agalactiae, Staphylococcus aureus, Bacillus anthracis, also against the two Gram negative bacteria: Klebsiella pneumoniae and Pseudomonas aeruginosa.
机译：从单阴离子配体CL3X（X = No3，CH3COO，N3）衍生出通式为Na [AlCl3 X]的三铝酸盐（III）配合物的合成与表征。三氯硝酸铝酸钠，SCNA，三氯乙酰铝酸钠，SCAA，三氯叠氮铝酸钠，SCAZA生产了三离子铝酸盐络合物。通过AlCl3与相关配体的直接反应，它们可以以接近定量的产率轻松合成。这些化合物通过IR，UV / Visible和Mass技术表征。关于化合物的分子结构，具有四个sp3杂化轨道的AL（III）阳离子（2S2,2P66）可以与两种配位原子3Cl，X原子形成稳定的英雄络合物，X原子可以与（AL）离子配位。 AL和Cl，X原子和标题配体是无序的。建议结构变形远离理想的C3V几何形状。研究了合成化合物对四种革兰氏阳性细菌：化脓性链球菌，无乳链球菌，金黄色葡萄球菌，炭疽芽孢杆菌的抗菌活性，还对两种革兰氏阴性细菌：肺炎克雷伯菌和铜绿假单胞菌具有抗菌作用。

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