首页> 外文期刊>Turkish Journal of Agriculture & Forestry >Utilization of boron compounds as synergists with ammonium polyphosphate for flame retardant wood-polymer composites
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Utilization of boron compounds as synergists with ammonium polyphosphate for flame retardant wood-polymer composites

机译:硼化合物与聚磷酸铵作为增效剂用于阻燃木塑复合材料

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The investigation consisted of utilizing boron compounds (BCs) as a synergist with ammonium polyphosphate (APP) in manufacturing flame retardant wood-polymer composites (WPCs). Flame retardants (FRs) at various ratios (APP, boric acid (BA), borax (BX), zinc borate and BA/BX mixtures) were used to determine the physical, mechanical, and burning rate properties of WPCs manufactured from wood flour, polypropylene, and maleic anhydride polypropylene. The results showed that the addition of FRs reduced all mechanical properties of WPCs except for impact strength. However, this reduction was lower for samples having BCs in FRs formulation. Similar burning rate results were achieved in WPCs having FRs. The combination of BA/BX with APP is thought to have overcome the negative effect of APP on strength properties through the formation of boron phosphate between APP and BA. BCs, used as the synergist, improved the mechanical and FRs performance of WPCs. This study showed that using BCs as synergists with APP has potential as a relatively inexpensive halogen-free FR alternative for the industry. Key words: Ammonium polyphosphate, boron, boron phosphate, flame retardants, polypropylene, wood-polymer composite
机译:该研究包括利用硼化合物(BCs)与多磷酸铵(APP)协同作用来制造阻燃性木材-聚合物复合材料(WPC)。使用各种比例的阻燃剂(FRs)(APP,硼酸(BA),硼砂(BX),硼酸锌和BA / BX混合物)确定由木粉制成的WPC的物理,机械和燃烧速率特性,聚丙烯和马来酸酐聚丙烯。结果表明,添加阻燃剂会降低木塑复合材料的所有机械性能(冲击强度除外)。但是,对于具有FRs配方中的BCs的样品,这种降低幅度较小。在具有阻燃剂的WPC中获得了相似的燃烧速率结果。认为BA / BX与APP的结合通过在APP与BA之间形成磷酸硼,克服了APP对强度性能的不利影响。用作增效剂的BC提高了WPC的机械性能和阻燃性能。这项研究表明,使用BCs作为APP的增效剂,具有作为行业中相对便宜的无卤FR替代品的潜力。关键词:聚磷酸铵硼磷酸硼阻燃剂聚丙烯木材-聚合物复合材料

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