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Phase Equilibrium Study of Extraction and Concentration of Furfural Produced in Reactor Using Supercritical Carbon Dioxide

机译:超临界二氧化碳萃取和浓缩反应器中糠醛的相平衡研究

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References(11) Cited-By(36) To obtain fundamental data for the extraction and concentration of furfural produced in a reactor by using supercritical CO2, the isothermal high pressure vapor–liquid equilibria for two binary systems (CO2–water and CO2–furfural) and a ternary system (CO2–water–furfural) were measured in the temperature range from 343 to 421 K. Additionally, the experimental data were compared with results calculated by various equations of state. As a result, it was found that (1) the Peng–Robinson and Soave–Redlich–Kwong equations of state combined with the mixing rules proposed by Panagiotopoulos correlated the two binary systems satisfactorily and predicted the ternary system well, and (2) the furfural produced could be selectively extracted from the reactor and concentrated to 95 wt% by a new process proposed on the basis of a knowledge of the vapor–liquid equilibria.
机译:参考文献(11)Cited-By(36)要获得提取和浓缩反应堆中糠醛的基本数据,其中使用超临界CO2是两个二元系统(CO2-水和CO2-糠醛的等温高压汽-液平衡) )和三元体系(CO 2-水-糠醛)在343至421 K的温度范围内进行了测量。此外,将实验数据与各种状态方程计算的结果进行了比较。结果发现,(1)Peng-Robinson和Soave-Redlich-Kwong状态方程与Panagiotopoulos提出的混合规则相结合,令人满意地关联了两个二元系统,并很好地预测了三元系统,以及(2)可以从反应器中选择性地提取产生的糠醛,并通过在汽液平衡知识基础上提出的新方法将其浓缩至95 wt%。

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