Thermal Decomposition Study of Ferrocene [(C5H5)2Fe]

AshisBhattacharjee; AmlanRooj; DebasisRoy; MadhusudanRoy

首页> 外文期刊>Journal of Experimental Physics >Thermal Decomposition Study of Ferrocene [(C5H5)2Fe]

【24h】

Thermal Decomposition Study of Ferrocene [(C5H5)2Fe]

机译：二茂铁[（C5H5）2Fe]的热分解研究

获取原文

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A single-step thermal decomposition of ferrocene [(C5H5)2Fe] using nonisothermal thermogravimetry (TG) has been studied using single- as well as multiple-heating rate programs. Both mechanistic and nonmechanistic methods have been used to analyze the TG data to estimate the kinetic parameters for the solid state reaction. Two different isoconversional methods (improved iterative method and model-free method) have been employed to analyze the TG results to find out whether the activation energy of the reaction depends on the extent of decomposition and to predict the most probable reaction mechanism of thermal decomposition as well. A comparison of the activation energy values for the single-step thermal reaction of ferrocene estimated by different methods has been made in this work. An appraisal on the applicability of single-heating rate data for the analysis of single-step thermal decompositions over the recommendations by the International Confederation for Thermal Analysis and Calorimetry (ICTAC) is made to look beyond the choice.

机译：使用非等温热重法（TG）研究了二茂铁[（C5H5）2Fe]的单步热分解，并使用了单升温速率程序和多升温速率程序。力学方法和非力学方法都已用于分析TG数据，以估算固态反应的动力学参数。两种不同的等转化方法（改进的迭代方法和无模型方法）已被用于分析TG结果，以查明反应的活化能是否取决于分解程度，并预测最可能的热分解反应机理。好。在这项工作中，对通过不同方法估算的二茂铁单步热反应的活化能值进行了比较。根据国际热分析与量热学联合会（ICTAC）的建议，对单加热速率数据在分析单步热分解中的适用性进行了评估，超出了选择范围。

著录项

来源
《Journal of Experimental Physics》 |2014年第1期|共8页
作者
AshisBhattacharjee; AmlanRooj; DebasisRoy; MadhusudanRoy;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种
中图分类物理学;
关键词

相似文献

外文文献
中文文献
专利

1. Synthesis of Si-C-N-Fe films from volatile organosilicon substances-precursors and ferrocene. Part II. Properties of SiC (x) N (y) Fe (z) films obtained by thermal decomposition of tris(diethylamino)silane and ferrocene [J] . Pushkarev R. V., Fainer N. I., Golubenko A. N., Glass Physics and Chemistry: A Journal on the Structural, Physical, and Chemical Properties and Nature of Inorganic Glasses and Glass-Forming Melts . 2016,第5期

机译：由挥发性有机硅物质-前体和二茂铁合成Si-C-N-Fe薄膜。第二部分通过三（二乙氨基）硅烷和二茂铁的热分解获得的SiC（x）N（y）Fe（z）膜的性能
2. Synthesis of Si-C-N-Fe layers from volatile organosilicon precursors and ferrocene. part I. synthesis, chemical and phase composition of iron-containing layers prepared by thermal decomposition of ferrocene [J] . Fainer N. I., Pushkarev R. V., Golubenko A. N., Glass Physics and Chemistry: A Journal on the Structural, Physical, and Chemical Properties and Nature of Inorganic Glasses and Glass-Forming Melts . 2015,第6期

机译：由挥发性有机硅前体和二茂铁合成Si-C-N-Fe层。第一部分。通过二茂铁的热分解制备的含铁层的合成，化学和相组成
3. Synthesis and correlation study on the morphology and Raman spectra of CN_x nanotubes by thermal decomposition of ferrocene/ethylenediamine [J] . E. J. Liang, P. Ding, H. R. Zhang Diamond and Related Materials . 2004,第1期

机译：二茂铁/乙二胺热分解制备CN_x纳米管的形貌和拉曼光谱及其相关性研究
4. ~(57)Fe Moessbauer Studies of the Bulky Ring-Substituted Ferrocenes; C_5Me_4(p-C_6H_4Y)_2Fe [C] . M. BJOERGVINSSON, O. HELGASON, M. H. HARALDSSON International symposium on the industrial applications of the mossbauer effect . 2002

机译：〜（57）Fe Moessbauer对庞大的环取代的铁致纤维素的研究; C_5ME_4（P-C_6H_4Y） _ 2FE
5. Powerful three-component/one-pot asymmetric protocol for synthesizing chiral tryptophan derivatives, and, An investigation into the decomposition of borane-tetrahydrofuran complex in tetrahydrofuran through accelerated thermal decomposition studies and stabilization by Lewis base [D] . Todd, Robert C. 2008

机译：强大的三组分/一锅不对称合成手性色氨酸衍生物的方法，以及通过加速热分解研究和路易斯碱稳定化研究四氢呋喃中硼烷-四氢呋喃配合物的分解
6. Experimental and Theoretical Mechanistic Study on the Thermal Decomposition of 33-diphenyl-4-(trichloromethyl)-5-nitropyrazoline [O] . Karolina Kula, Agnieszka Kącka-Zych, Agnieszka Łapczuk-Krygier, 2021

机译：33-二苯基-4-（三氯甲基）-5-硝基吡唑啉的热分解的实验与理论力学研究
7. Evidence of quasi-intramolecular redox reactions during thermal decomposition of ammonium hydroxodisulfitoferriate(III), (NH4)2Fe(OH)(SO3)2·H2O [O] . Tünde Kocsis, József Magyari, István E. Sajó, 2017

机译：羟二硫酸铵（III）热分解期间准分子内氧化还原反应的证据，（NH4）2 Fe（OH）（SO 3）2·H2O
8. Thermal Decomposition of 2,5-Dipicryl-1,3,4-Oxadiazole, Near its IgnitionTemperature: An Isothermal DSC Study [R] . Whelan, D. J., Fitzgerald, M. R. 1994

机译：2,5-二吡啶-1,3,4-恶二唑的热分解，接近其点火温度：等温DsC研究

Thermal Decomposition Study of Ferrocene [(C5H5)2Fe]

摘要

著录项

相似文献

相关主题

期刊订阅