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Synthesis of MgB4O7:Dy3+ and Thermoluminescent Characteristics at Low Doses of Beta Radiation

机译:低剂量β辐射下MgB 4 O 7 :Dy 3 + 的合成及热致发光特性

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The synthesis and thermoluminescent characteristics of dysprosium-doped MgB_(4)O_(7) are analyzed. The phosphor at different concentrations (0, 0.1, 0.5, 1, 2 and 4 mol%) of the dopant was prepared by the solution-assisted method. The magnesium borate compound was confirmed by X-ray diffraction. The annealing and dopant concentrations effects on the crystalline matrix were investigated. The highest thermoluminescent sensitivity was found with 450°C of annealing temperature and at high Dy~(3+) concentration too. The un-doped MgB_(4)O_(7) phosphor shows a broad glow curve which peaked at 199°C and about 306 °C. Introducing Dy~(3+) dopant in the matrix that behavior was strongly changed. The wide glow curve shows three glow peaks; two small shoulders at 124 and 195 °C, and a highest peak between 323 and 336 °C temperature range. A large linear dose-response (5 – 2000 mGy) beta dose was obtained. The complex glow curves were deconvolved and the kinetics parameters were determined considering the general order kinetics model.
机译:分析了掺dy的MgB_(4)O_(7)的合成和热致发光特性。通过溶液辅助法制备不同浓度(0、0.1、0.5、1、2和4mol%)的掺杂剂的磷光体。硼酸镁化合物通过X射线衍射确认。研究了退火和掺杂剂浓度对晶体基质的影响。在450℃的退火温度和高的Dy〜(3+)浓度下也发现了最高的热致发光灵敏度。未掺杂的MgB_(4)O_(7)磷光体显示出宽辉光曲线,该辉光曲线在199°C和约306°C时达到峰值。在基质中引入Dy〜(3+)掺杂剂,可以改变其行为。宽辉光曲线显示三个辉光峰。在124和195°C时有两个小肩部,最高峰值在323和336°C之间。获得了大的线性剂量反应(5-20​​00 mGy)β剂量。对复杂的辉光曲线进行反卷积,并考虑一般顺序动力学模型确定动力学参数。

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