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Preparation of the Oriented Polycrystalline BaTi2O5 Ferroelectric Ceramics

机译:取向多晶BaTi2O5铁电陶瓷的制备

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The dense and oriented BaTi2O5 (BT2) in a single phase was successfully obtained by an arc melting process on a water-cooled copper plate using BaCO3 and TiO2 as starting materials and B2O3 as an additive. XRD pattern of BT2 showed a preferred orientation of (020). The microstructure of BT2 was examined to show a needle-like shape and the BT2 grains were 3~15 μm in diameters and 22~110 μm in lengths. Though B2O3 was effective to prepare dense BT2, it, disadvantageously, tended to decrease the permittivity of BT2. The discrepancy of the peak frequencies between Z″ and M″ could be ascribed to the existence of structural defects and occurrence of the second phase. The maximum permittivity was 863 when the frequency (f) and the Curie temperature (Tc) were 100 kHz and 465°C, respectively.
机译:以BaCO3和TiO2为起始原料,以B2O3为添加剂,通过水冷铜板上的电弧熔化工艺成功获得了单相致密取向的BaTi2O5(BT2)。 BT2的XRD图谱显示了(020)的优选方向。检查BT2的微观结构以显示出针状形状,并且BT2晶粒的直径为3〜15μm,长度为22〜110μm。尽管B 2 O 3能有效地制备致密的BT 2,但不利的是,它倾向于降低BT 2的介电常数。 Z″和M″之间的峰值频率的差异可以归因于结构缺陷的存在和第二相的出现。当频率(f)和居里温度(Tc)分别为100 kHz和465°C时,最大介电常数为863。

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