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Characterizations of optical properties and radiation induced luminescence of Bi-doped La2Zr2O7 transparent ceramics

机译:双掺杂La2Zr2O7透明陶瓷的光学性质和辐射致发光的表征

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We have investigated the optical and scintillation properties of La2Zr2O7 transparent ceramics doped with 0–0.46% Bi. In the photoluminescence (PL), an intense broad emission was observed around 600 nm, and the primary PL decay time was 1.2 μs. The origin of the emission was attributed to the Bi3+ related luminescence. The 0.10% Bi doped sample showed the highest PL quantum yield (70%) among the samples measured. In the X-ray induced scintillation spectra, a similar emission features to those observed in PL spectra were observed. The scintillation emission was not observed at low temperatures below 200 K and Bi emission around room temperature was promoted by the thermal activation.
机译:我们研究了掺有0-0.46%Bi的La 2 Zr 2 O 7 透明陶瓷的光学和闪烁特性。在光致发光(PL)中,在600 nm附近观察到强烈的宽发射,并且初级PL衰减时间为1.2μs。发光的起源归因于与Bi 3 + 相关的发光。在所测样品中,掺0.10%Bi的样品显示出最高的PL量子产率(70%)。在X射线诱发的闪烁光谱中,观察到与PL光谱中观察到的那些相似的发射特征。在低于200 K的低温下未观察到闪烁发射,并且通过热活化促进了室温附近的Bi发射。

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