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首页> 外文期刊>Journal of spectroscopy >Investigation of Charge Transfer Complexes Formed between Mirtazapine and Someπ-Acceptors
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Investigation of Charge Transfer Complexes Formed between Mirtazapine and Someπ-Acceptors

机译：米氮平与某些π受体形成的电荷转移配合物的研究

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摘要

Charge transfer complexes (CTC) of mirtazapine with tetracyanoethylene (TCNE), 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ), and tetracyanoquinodimethane (TCNQ) have been studied spectrophotometrically in dichloromethane at room temperature. The stoichiometries of the complexes were found to be 1 : 1 ratio by the Job Method between mirtazapine and the acceptors. The equilibrium constants and thermodynamic parameters of the complexes were determined by the Benesi-Hildebrand and Van't Hoff equations. Mirtazapine in pure and dosage form was applied in this study. The results indicate that the formation constants for the complexes depend on the nature of electron acceptors and donor. And also the spectral studies of the complexes were determined by FT-IR and NMR spectroscopy.
机译：米色氮平与四氰基乙烯（TCNE），2,3-二氯-5,6-二氰基对苯醌（DDQ）和四氰基喹二甲烷（TCNQ）的电荷转移络合物（CTC）在室温下在二氯甲烷中进行了分光光度法研究。通过工作方法发现米氮平与受体之间的配合物的化学计量比为1：1。络合物的平衡常数和热力学参数由Benesi-Hildebrand和Van't Hoff方程确定。本研究采用纯净的米氮平和剂型。结果表明，络合物的形成常数取决于电子受体和给体的性质。并通过FT-IR和NMR光谱确定了配合物的光谱研究。

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