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Butane-1,4-diammonium bis(perchlorate)

机译:1,4-丁二铵双(高氯酸盐)

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摘要

The butane-1,4-diammonium cation of the title compound, C4H14N22+·2ClO4?, lies on a special position of site symmetry 2/m, whereas the perchlorate anion is located on a crystallographic mirror plane. An intricate three-dimensional hydrogen-bonding network exists in the crystal structure with each H atom of the ammonium group exhibiting bifurcated inter-actions to the perchlorate anion. Complex hydrogen-bonded ring and chain motifs are also evident, in particular a 50-membered ring with graph-set notation R1010(50) is identified.
机译:标题化合物C4H14N22 +·2ClO4的-1,4-丁烷阳离子位于位置对称的特殊位置2 / m,而高氯酸根阴离子位于晶体镜面上。晶体结构中存在复杂的三维氢键网络,铵基团的每个H原子与高氯酸根阴离子表现出分叉的相互作用。复杂的氢键结合的环和链基序也很明显,特别是鉴定出具有图形集符号R1010(50)的50元环。

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