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首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Bis(acetato-κ2O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)copper(II) monohydrate
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Bis(acetato-κ2O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)copper(II) monohydrate

机译:一水合双(乙酰-κ2O,O')(4,4'-二甲基-2,2'-联吡啶-κ2N,N')铜(II)

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摘要

In the title compound, [Cu(C2H3O2)2(C12H12N2)2]·H2O, the CuII atom exhibits a distorted octa-hedral coordination geometry, defined by two N atoms from one 4,4′-dimethyl-2,2′-bipyridine ligand and four O atoms from two acetate ligands. In the crystal, O—H?O hydrogen bonds are observed between the coordinated carboxyl-ate O atoms and the solvent water mol-ecule.
机译:在标题化合物[Cu(C2H3O2)2(C12H12N2)2]·H2O中,CuII原子表现出扭曲的八面体配位几何形状,由一个4,4'-二甲基-2,2'-中的两个N原子定义联吡啶配体和来自两个乙酸酯配体的四个O原子。在晶体中,在配位的羧酸根O原子与溶剂水分子之间观察到OH-氢键。

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