Na2.9KMo12S14: a novel quaternary reduced molybdenum sulfide containing Mo12 clusters with a channel structure

Gall P.; Gougeon P.; Salloum D.

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Na2.9KMo12S14: a novel quaternary reduced molybdenum sulfide containing Mo12 clusters with a channel structure

机译：Na2.9KMo12S14：一种新型的季铵还原的含钼的硫化钼，具有通道结构

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The crystal structure of tris-odium potassium dodeca-molybdenum tetra-deca-sulfide, Na2.9?(2)KMo12S14, consists of Mo12S14S6 cluster units inter-connected through inter-unit Mo—S bonds and delimiting channels in which the Na+ cations are disordered. The cluster units are centered at Wyckoff positions 2d and have point-group symmetry 3.2. The K atom lies on sites with 3.2 symmetry (Wyckoff site 2c) between two consecutive Mo12S14S6 units. One of the three independent S atoms and one Na atom lie on sites with 3.. symmetry (Wyckoff sites 4e and 4f). The other Na atom occupies a 2b position with -3.. symmetry. The crystal studied was a merohedral twin with refined components of 0.4951?(13) and 0.5049?(13).

机译：十二硫化三钠钾四硫化钠钼的晶体结构Na2.9？（2）KMo12S14由通过单元间Mo-S键和Na +阳离子在其中划定通道的互连的Mo12S14S6簇单元组成无序。聚类单元在Wyckoff位置2d处居中，并具有点组对称性3.2。 K原子位于两个连续的Mo12S14S6单元之间具有3.2对称性的位点（Wyckoff位点2c）。三个独立的S原子之一和一个Na原子位于3 ..对称的位点上（Wyckoff位点4e和4f）。另一个Na原子以-3 ..对称性占据2b位置。研究的晶体是具有0.4951？（13）和0.5049？（13）的精炼成分的多面体孪晶。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2013年第6期|共页
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Gall P.; Gougeon P.; Salloum D.;
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1. Na2.9KMo12S14: a novel quaternary reduced molybdenum sulfide containing Mo12 clusters with a channel structure [J] . Gall P., Gougeon P., Salloum D. Acta Crystallographica Section E: Crystallographic Communications . 2013,第6期

机译：Na2.9KMo12S14：一种新型的季铵还原的含钼的硫化钼，具有通道结构
2. Synthesis, Crystal and Electronic Structures, and Electrical Properties of the Fifth Member of the Rb-2(Mo9S11)(Mo6nS6n+2 ) Series: Rb10Mo39S43, an Atypical Reduced Molybdenum Sulfide Containing Mo(9 )and Mo-30 Clusters [J] . Gougeon Patrick, Gall Philippe, Huguenot Arthur, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2019,第22期

机译：RB-2（MO9S11）（MO6NS11）（MO6NS11）（MO6NS6N + 2）系列的第五成分的合成，晶体和电子结构，以及含有MO（9）和MO-30簇的非典型减少的钼硫化物
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机译：氧化钼与硫化钼：Mo_3X y-（X = O，S和y = 6，9）簇的几何和电子结构
4. Tribochemistry of Friction-Reducing Molybdenum Sulfide Nano-Additive [C] . V. N. Bakunin, G. N. Kuzmina, O. P. Parenago, International Colloquium Tribology . 2006

机译：减少摩尔硫化钼硫化物纳米添加剂的培养学化学
5. Synthesis of the clusters with the molybdenum iron sulfide core and core rearrangements of molybdenum/iron/sulfur clusters under reducing conditions . [D] . Han, Jaehong. 2001

机译：钼铁硫核团簇的合成及还原条件下钼/铁/硫团簇的核重排。
6. Na2.9KMo12S14: a novel quaternary reduced molybdenum sulfide containing Mo12 clusters with a channel structure [O] . Patrick Gougeon, Philippe Gall, Diala Salloum 2013

机译：Na2.9KMo12S14：一种新型的季铵还原的硫化钼含具有通道结构的Mo12簇
7. Na2.9KMo12S14: a novel quaternary reduced molybdenum sulfide containing Mo12 clusters with a channel structure [O] . Patrick Gougeon, Philippe Gall, Diala Salloum 2013

机译：Na2.9KMo12S14：一种新型的季铵还原的硫化钼，含具有通道结构的Mo12簇
8. Low temperature pathways to Chevrel phases via reduced molybdenum sulfide cluster complexes. [R] . Shane, H. 1993

机译：通过还原的硫化钼簇络合物到Chevrel相的低温途径。

Na2.9KMo12S14: a novel quaternary reduced molybdenum sulfide containing Mo12 clusters with a channel structure

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