Crystal structure of di-chlorido-bis-(dimethyl N-cyano-dithio-imino-carbonate)cobalt(II)

Diop M.B.; Diop L.; Oliver A.G.

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Crystal structure of di-chlorido-bis-(dimethyl N-cyano-dithio-imino-carbonate)cobalt(II)

机译：二氯双-（二甲基N-氰基-二硫代-亚氨基碳酸酯）钴的晶体结构（II）

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The structure of the mononuclear title complex, [{(H3CS)2C=NC≡ N}2CoCl2], consists of a CoII atom coordinated in a distorted tetra-hedral manner by two Cl? ligands and the terminal N atoms of two dimethyl N-cyano-dithio-imino-carbonate ligands. The two organic ligands are almost coplanar, with a dihedral angle of 5.99?(6)° between their least-squares planes. The crystal packing features pairs of inversion-related complexes that are held together through C—H?Cl and C—H?S inter-actions and π–π stacking [centroid-to-centroid distance = 3.515 (su?) ?]. Additional C—H?Cl and C—H?S inter-actions, as well as Cl?S contacts < 3.6??, consolidate the crystal packing.

机译：单核标题配合物的结构[{（（H3CS）2C =NC≡N} 2CoCl2]，由CoII原子组成，该CoII原子以扭曲的四面体方式由两个Cl？配体和两个二甲基N-氰基-二硫代-亚氨基碳酸酯配体的末端N原子。两种有机配体几乎共面，它们的最小二乘平面之间的二面角为5.99？（6）°。晶体堆积具有成对的与反转有关的络合物，这些络合物通过CH-Cl和CH-S相互作用以及π-π堆积[质心间的距离= 3.515（su？）？]结合在一起。额外的CH 3 Cl和CH 3 S相互作用以及Cl 2 S接触度＜3.6 5，巩固了晶体堆积。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2016年第1期|共3页
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Diop M.B.; Diop L.; Oliver A.G.;
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Crystal structure of di-chlorido-bis-(dimethyl N-cyano-dithio-imino-carbonate)cobalt(II)

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