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首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of bis­[S-hexyl 3-(4-methyl­benzyl­idene)di­thio­carbazato-κ2N3,S]nickel(II)
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Crystal structure of bis­[S-hexyl 3-(4-methyl­benzyl­idene)di­thio­carbazato-κ2N3,S]nickel(II)

机译:双[S-己基3-(4-甲基亚苄基)二硫代氨基甲酸-κ2N3,S]镍(II)的晶体结构

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摘要

In the title complex, [Ni(C15H21N2S2)2], the NiII atom exhibits a square-planar coordination geometry and is located on an inversion centre leading to a trans configuration of the N,S-chelating ligands. In the crystal, the complex mol­ecules stack at a distance of 4.6738 (3) Å along the a axis, which exclude any significant inter­actions between the aromatic rings.
机译:在标题配合物[Ni(C15H21N2S2)2]中,NiII原子表现出方平面配位几何形状,位于一个反转中心,导致N,S-螯合配体的反式构型。在晶体中,复杂分子沿a轴的距离为4.6738(3)Å,这排除了芳环之间的任何重要相互作用。

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