Crystal structures of the polymer precursors 3-(2,5-dimeth-oxy-3,4,6-tri-methyl-phen-yl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxo-cyclo-hexa-1,4-dien-yl)propyl methacrylate

Goswami S.K.; Hanton L.R.; McAdam C.J.; Moratti S.C.; Simpson J.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structures of the polymer precursors 3-(2,5-dimeth-oxy-3,4,6-tri-methyl-phen-yl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxo-cyclo-hexa-1,4-dien-yl)propyl methacrylate

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Crystal structures of the polymer precursors 3-(2,5-dimeth-oxy-3,4,6-tri-methyl-phen-yl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxo-cyclo-hexa-1,4-dien-yl)propyl methacrylate

机译：聚合物前体甲基丙烯酸3-（2,5-二甲基氧基-3,4,6-三甲基苯甲酰基）丙酯和3-（2,4,5-三甲基-3,6-二氧杂）的晶体结构甲基丙烯酸-环-六-1,4-二烯基）丙酯

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The closely related title compounds, 3-(2,5-dimeth-oxy-3,4,6-tri-methyl-phen-yl)propyl methacrylate, C18H26O4 (I), and 3-(2,4,5-trimethyl-3,6-dioxo-cyclo-hexa-1,4-dien-yl)propyl methacrylate, C16H20O4 (II), are monomers suitable for the preparation of redox polymers. They consist of a propyl-methacrylate group and three methyl substituents on di-meth-oxy-benzene and quinone cores, respectively. Both crystal structures feature weak C—H?O hydrogen bonds and C—H?π(ring) contacts between methyl groups and the six-membered rings.

机译：密切相关的标题化合物甲基丙烯酸3-（2,5-二甲基氧基-3,4,6-三甲基-苯甲酰基）丙酯，C18H26O4（I）和3-（2,4,5-三甲基甲基丙烯酸-3,6-二氧代环-环-1,4-二烯基）丙基酯C16H20O4（II）是适用于制备氧化还原聚合物的单体。它们由甲基丙烯酸丙酯基和分别在二甲基氧基苯和醌核上的三个甲基取代基组成。两种晶体结构均具有弱的CHHO氢键和甲基与六元环之间的CHHπ（环）接触。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第5期|共6页
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Goswami S.K.; Hanton L.R.; McAdam C.J.; Moratti S.C.; Simpson J.;
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1. Crystal structures of the polymer precursors 3-(2,5-dimeth-oxy-3,4,6-tri-methyl-phen-yl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxo-cyclo-hexa-1,4-dien-yl)propyl methacrylate [J] . Goswami S.K., Hanton L.R., McAdam C.J., Acta Crystallographica Section E: Crystallographic Communications . 2017,第5期

机译：聚合物前体甲基丙烯酸3-（2,5-二甲基氧基-3,4,6-三甲基苯甲酰基）丙酯和3-（2,4,5-三甲基-3,6-二氧杂）的晶体结构甲基丙烯酸-环-六-1,4-二烯基）丙酯
2. Preparation of organic/inorganic hybrid nanomaterials using aggregates of star block copolymer consisting of poly(stearyl methacrylate) and poly(3-(trimethoxysilyl) propyl methacrylate) as precursor [J] . Zhou JF, Wang L, Dong XC, Journal of Applied Polymer Science . 2008,第3期

机译：以聚甲基丙烯酸硬脂酯和甲基丙烯酸3-（三甲氧基甲硅烷基）丙酯组成的星形嵌段共聚物的聚集体制备有机/无机杂化纳米材料
3. Preparation of organic/inorganic hybrid nanomaterials using aggregates of poly(stearyl methacrylate)-b-poly(3-(trimethoxysilyl) propyl methacrylate) as precursor [J] . Zhou JF, Wang L, Dong XC, European Polymer Journal . 2007,第5期

机译：以聚（甲基丙烯酸硬脂基酯）-b-聚（甲基丙烯酸3-（三甲氧基甲硅烷基）丙酯）为骨料的有机/无机杂化纳米材料的制备
4. Gel polymer electrolyte from ozonolysis of poly(3-(trimethoxysilyl) propyl methacrylate) graft on natural rubber latex for natural dye sensitized solar cell application [C] . Pensiri Silakul, Rathanawan Magaraphan Asia Pacific Rubber Conference . 2014

机译：凝胶聚合物电解质来自聚（3-（三甲氧基甲硅烷基）丙基丙烯酸丙烯酸丙酯）移植物，天然橡胶胶乳溶液敏化太阳能电池应用
5. Studies of the RAFT polymerization of acrylamide and N-[3-(dimethylamino)propyl] methacrylamide: Factors affecting kinetics, molecular weight control, and block copolymer formation. [D] . Thomas, David Bryan. 2003

机译：丙烯酰胺和N- [3-（二甲基氨基）丙基]甲基丙烯酰胺的RAFT聚合研究：影响动力学，分子量控制和嵌段共聚物形成的因素。
6. Crystal structures of the polymer precursors 3-(25-dimethoxy-346-trimethylphenyl)propyl methacrylate and 3-(245-trimethyl-36-dioxocyclohexa-14-dienyl)propyl methacrylate [O] . Shailesh K. Goswami, Lyall R. Hanton, C. John McAdam, 2017

机译：聚合物前体甲基丙烯酸3-（25-二甲氧基-346-三甲基苯基）丙基和3-（245-三甲基-36-二氧代环己-14-二烯基）丙基的晶体结构甲基丙烯酸酯
7. Crystal structures of the polymer precursors 3-(2,5-dimethoxy-3,4,6-trimethylphenyl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)propyl methacrylate [O] . Shailesh K. Goswami, Lyall R. Hanton, C. John McAdam, 2017

机译：聚合物前体3-（2,5-二甲氧基-3,4,6-三甲基苯基）丙基甲基丙烯酸酯和3-（2,4,5-三甲基-3,6-二氧代环己-1,4-二烯基）丙基的晶体结构甲基丙烯酸甲酯
8. Evaluation of the Ability of Reaction Mass of ((3-(2,3-epoxypropoxy)propyl)trimethoxy)silane and triacetoxyvinylsilane to Induce Chromosome Aberrations in Cultured Peripheral Human Lymphocytes with Silanetriol, Ethenyl, Triacetate, Reaction Products with Trimethoxy (3-(oxiranylmethoxy)propyl) Silane. [R] . 2015

机译：评价（（3-（2,3-环氧丙氧基）丙基）三甲氧基）硅烷和三乙酰氧基乙烯基硅烷的反应质量能够诱导培养的外周人淋巴细胞染色体畸变用硅烷三醇，乙烯，三乙酸酯，三甲氧基反应产物（3-（环氧乙烷基甲氧基）丙基）硅烷。

Crystal structures of the polymer precursors 3-(2,5-dimeth-oxy-3,4,6-tri-methyl-phen-yl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxo-cyclo-hexa-1,4-dien-yl)propyl methacrylate

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