...
首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of bis­(4-benzoyl­pyridine-κN)bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)
【24h】

Crystal structure of bis­(4-benzoyl­pyridine-κN)bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)

机译:双(4-苯甲酰基吡啶-κN)双(甲醇-κO)双(硫氰酸根-κN)钴(II)的晶体结构

获取原文
           

摘要

The crystal structure of the title compound, [Co(NCS)2(C12H9NO)2(CH3OH)2], consists of cobalt(II) cations that are octa­hedrally coordinated by two N-terminal bonding thio­cyanato anions, two methanol mol­ecules and two 4-benzoyl­pyridine ligands into discrete complexes that are located on centres of inversion. These complexes are further linked by O—H⋯O hydrogen bonding between the hy­droxy H atom of the methanol ligand and the carbonyl O atom of the 4-benzoyl­pyridine ligand of a neighboring complex into layers parallel to (101). No pronounced inter­molecular inter­actions are observed between these layers.
机译:标题化合物[Co(NCS)2(C12H9NO)2(CH3OH)2]的晶体结构由钴(II)阳离子组成,该阳离子由两个N端键合的硫氰酸根阴离子,两个甲醇分子和两个4组成八面体配位。 -苯甲酰基吡啶配体变成位于反转中心的离散复合物。这些配合物通过甲醇配体的羟基H原子与相邻配合物的4-苯甲酰基吡啶配体的羰基O原子之间的OH氢键进一步连接成平行于(101)的层。在这些层之间没有观察到明显的分子间相互作用。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号