Crystal structure of catena-poly[[tri­methyl­tin(IV)]-μ-2-(2-nitro­phen­yl)acetato-κ2O:O′]

Danish M.; Tahir M.N.; Iftikhar S.; Raza M.A.; Ashfaq M.

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Crystal structure of catena-poly[[trimethyltin(IV)]-μ-2-(2-nitrophenyl)acetato-κ2O:O′]

机译：链状聚[[三甲基锡（IV）]-μ-2-（2-硝基苯基）乙酰-κ2O：O']的晶体结构

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In the title one-dimensional coordination polymer, [Sn(CH3)3(C8H6NO4)]n, the SnIV atom is coordinated by three methyl C atoms and two carboxylate O atoms (one symmetry generated), resulting in an almost regular SnC3O2 trigonal pyramid. The C atoms occupy the equatorial sites and the O atoms occupy the axial sites. In the ligand, the dihedral angles between the benzene ring and the pendant acetate and nitro groups are 57.7 (1) and 36.9 (3)°, respectively. The bridging ligand leads to [010] chains in the crystal, with adjacent metal atoms related by a 21 screw axis. A weak π–π interaction exists between the centroids of symmetry-related benzene rings at a distance of 3.9131 (19) Å.

机译：在标题一维配位聚合物[Sn（CH3）3（C8H6NO4）] n中，SnIV原子由三个甲基C原子和两个羧基O原子配位（产生一个对称性），从而形成了几乎规则的SnC3O2三棱锥。 C原子占据赤道位点，O原子占据轴向位点。在该配体中，苯环与乙酸酯侧基和硝基之间的二面角分别为57.7°（1）和36.9°（3）°。桥连的配体导致晶体中的[010]链，相邻的金属原子由21个螺旋轴关联。对称相关苯环的重心之间存在弱的π-π相互作用，距离为3.9131（19）Å。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2015年第3期|共页
作者
Danish M.; Tahir M.N.; Iftikhar S.; Raza M.A.; Ashfaq M.;
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中图分类晶体学;
关键词
CRYSTAL STRUCTUREONE-DIMENSIONAL COORDINATION POLYMERTRIMETHYLTIN(IV) COMPLEXPI-PI INTERACTION;

机译：晶体结构一维配位聚合物三甲基锡（IV）络合物[PI]-[PI]的相互作用;

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1. Crystal structure of catena-poly[[trimethyltin(IV)]-μ-2-(2-nitrophenyl)acetato-κ2O:O′] [J] . Danish M., Tahir M.N., Iftikhar S., Acta Crystallographica Section E: Crystallographic Communications . 2015,第3期

机译：链状聚[[三甲基锡（IV）]-μ-2-（2-硝基苯基）乙酰-κ2O：O']的晶体结构
2. catena-Poly[[{diaqua[2-(4-hydroxyphenyl)acetato-κ2O,O′]cerium(III)}-bis[μ-2-(4-hydroxyphenyl)acetato]-κ3O,O′:O;κ3O:O,O′] 4,4′-bipyridine disolvate monohydrate] [J] . Liu J.-F., Liu J.-L., Zhao G.-L. Acta Crystallographica Section E: Crystallographic Communications . 2010,第12期

机译：阳离子-聚[[{{diaqua [2-（4-羟苯基）乙酸盐-κ2O，O']]铈（III）}-双[μ-2-（4-羟苯基乙酸盐）]-κ3O，O'：O;κ3O ：O，O'] 4,4'-联吡啶一水合物一水合物]
3. catena-Poly[[[aqua[(2-hydroxyphenyl)acetato-κ2O,O′]lead(II)]-μ3-[(2-hydroxyphenyl)acetato-κ4O:O,O′:O′]] monohydrate] [J] . Qin L., Wu X.-G., Xiao J.-X. Acta Crystallographica Section E: Crystallographic Communications . 2010,第3期

机译：catena-Poly [[[[[[2-羟基苯基）乙酸-κ2O，O']铅（II）]-μ3-[[2-羟基苯基]乙酸-κ4O：O，O'：O']]一水合物]
4. Computational modeling studies of the structures and properties of organotin(IV) and stannyl-thioether systems with comparisons to X-ray crystallography. [D] . Stem Joseph, Michelle R. 2009

机译：与X射线晶体学比较的有机锡（IV）和苯乙烯基-硫醚系统的结构和性能的计算建模研究。
5. Crystal structure of catena-polytrimethyltin(IV)-μ-2-(2-nitrophenyl)acetato-κ2O:O′ [O] . Muhammad Danish, Muhammad Nawaz Tahir, Sana Iftikhar, 2015

机译：链状聚三甲基（IV）-μ-2-（2-硝基苯甲酰基）乙酰基-κ2的晶体结构O：O
6. catena-Poly[[tris(4-fluorobenzyl)tin(IV)]-μ-2-[(piperidin-1-yl)carbothioylsulfanyl]acetato-κ2O:O′] [O] . Chun Thy Keng, Kong Mun Lo, Seik Weng Ng 2010

机译：阳离子-[[三（4-氟苄基）锡（IV）]-＆＃956; -2-[（哌啶-1-基）碳硫基硫烷基]乙酰基-＆＃954; 2O：O＆＃8242;]

Crystal structure of catena-poly[[tri­methyl­tin(IV)]-μ-2-(2-nitro­phen­yl)acetato-κ2O:O′]

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Crystal structure of catena-poly[[trimethyltin(IV)]-μ-2-(2-nitrophenyl)acetato-κ2O:O′]