Crystal structure of (±)-[trans-cyclo-hexane-1,2-diylbis(aza-nedi-yl)]di-phospho-nium dibromide dichloro-methane disolvate

Rodríguez álvarez A.; Tlahuext H.; Grévy J.-M.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of (±)-[trans-cyclo-hexane-1,2-diylbis(aza-nedi-yl)]di-phospho-nium dibromide dichloro-methane disolvate

【24h】

Crystal structure of (±)-[trans-cyclo-hexane-1,2-diylbis(aza-nedi-yl)]di-phospho-nium dibromide dichloro-methane disolvate

机译：（±）-[反式-环己烷-1，2-二基双（氮杂-二氮基）]二磷酸二溴鎓二氯甲烷二溶剂化物的晶体结构

获取原文

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The cation of the title solvated salt, C42H42N2P22+·2Br?·2CH2Cl2, lies on a crystallographic twofold rotation axis. The 1,2-di-amino-cyclo-hexane fragment has a chair conformation with two N atoms in a transoid conformation [N—C—C—N = 163.4?(2)°]. In the crystal, the cations are linked to the anions by N—H?Br and C—H?Br hydrogen bonds, forming a chain structure along the c axis. The di-chloro-methane mol-ecule takes part in the hydrogen-bond network through C—H?π and C—H?Br inter-actions.

机译：标题溶剂化盐C42H42N2P22 +·2Br2·2CH2Cl2的阳离子位于晶体学的两倍旋转轴上。 1，2-二氨基-环己烷片段具有椅子构型，其中两个N原子呈反式构型[NC-CN ＝163.4≤（2）°]。在晶体中，阳离子通过NH-Br和CH-Br氢键与阴离子连接，形成沿c轴的链结构。二氯甲烷分子通过CH-π和CH-Br相互作用参与氢键网络。

著录项

来源
《Acta Crystallographica Section E: Crystallographic Communications》 |2016年第4期|共4页
作者
Rodríguez álvarez A.; Tlahuext H.; Grévy J.-M.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种
中图分类晶体学;
关键词

相似文献

外文文献
中文文献
专利

1. 1,3-Bis(2,6-diisopropyl-phen-yl)-1H-imidazol-3-ium bromide dichloro-methane disolvate [J] . Berger M., Auner N., Sinke T., Acta Crystallographica Section E: Crystallographic Communications . 2012,第6期

机译：1,3-双（2,6-二异丙基-苯基）-1H-咪唑-3-溴化二氯甲烷二溶剂化物
2. 1,3-Bis(2,6-diisopropyl-phen-yl)-1H-imidazol-3-ium chloride dichloro-methane disolvate [J] . Berger M., Auner N., Bolte M. Acta Crystallographica Section E: Crystallographic Communications . 2012,第6期

机译：1,3-双（2,6-二异丙基-苯基）-1H-咪唑-3-氯化二氯甲烷二溶剂化物
3. Crystal structures of tris[1-oxopyridine-2-olato(1−)]silicon(IV) chloride chloroform-d1 disolvate, tris[1-oxopyridine-2-olato(1−)]silicon(IV) chloride acetonitrile unquantified solvate, and fac-tris[1-oxopyridine-2-thiolato(1−)]silicon(IV) chloride chloroform-d1 disolvate [J] . Kraft B.M., Brennessel W.W., Ryan A.E., Acta Crystallographica Section E: Crystallographic Communications . 2015,第12期

机译：氯化三[1-氧吡啶吡啶-2-olato（1-）]硅（IV）氯仿-d1的晶体结构，氯化三[1-氧吡啶吡啶-2-olato（1-）]硅（IV）乙腈的未溶剂化溶剂，和fac-tris [1-氧代吡啶-2-硫羟甲基（1-）]氯化硅（IV）氯仿-d1二溶剂化物
4. Crystal Structure, Phase Stability and Plastic Deformation Behavior of Ti-rich Ni_3(Ti,Nb) Single Crystals with Various Long-Period Ordered Structures [C] . Koji Hagihara, Tetsunori Tanaka, Takayoshi Nakano, Symposium on Integrative and Interdisciplinary Aspects of Intermetallics . 2005

机译：具有各种长期有序结构的Ti富含Ni_3（Ti，Nb）单晶的晶体结构，相位稳定性和塑性变形行为
5. I. CRYSTAL AND MOLECULAR STRUCTURE OF ANTITUMOR AGENT JATROPHATRIONE; II. CRYSTAL AND MOLECULAR STRUCTURES OF TWO PYRIMIDONE DIMERS; III. CRYSTAL AND MOLECULAR STRUCTURE OF PHTHALIC ANHYDRIDE; IV. SYNTHETIC STUDIES ON THE SIDE CHAINS OF CEPHALOTAXINE ESTERS, POTENT ANTICANCER AGENTS. [D] . CUTLER, ROBERT STEVEN -1

机译：一，抗老剂麻油酮的晶体和分子结构；二。两种嘧啶酮的晶体和分子结构；三，邻苯二甲酸酐的晶体和分子结构； IV。头孢洛辛酯，强效抗癌剂的侧链合成研究。
6. Crystal structure of (±)-trans-cyclohexane-12-diylbis(azanediyl)diphosphonium dibromide dichloromethane disolvate [O] . Aurora Rodríguez Álvarez, Hugo Tlahuext, Jean-Michel Grévy 2016

机译：（±）-反式-环己烷-12-二基双（氮杂二烯丙基）二二溴化二氯甲烷二甲酸酯的晶体结构
7. Crystal structure of (±)-[trans-cyclohexane-1,2-diylbis(azanediyl)]diphosphonium dibromide dichloromethane disolvate [O] . Aurora Rodríguez Álvarez, Hugo Tlahuext, Jean-Michel Grévy 2016

机译：（±） - [反式 - 环己烷-1,2-二基双（氮杂二基）]二膦二溴二氯甲烷二醇溶剂的晶体结构
8. DIFFRACTION OF X-RAY BY NON-IDEAL MOSAIC CRYSTALS AND THE STRUCTURES OF PLASTICALLY DEFORMED AND ANNEALED CRYSTALS OF ZINC [R] . Douglas W. Bainbridge, Jack Washburn, Earl R. Parker 1957

机译：非理想马赛克晶体X射线的衍射及锌的塑性变形和退火晶体的结构

Crystal structure of (±)-[trans-cyclo-hexane-1,2-diylbis(aza-nedi-yl)]di-phospho-nium dibromide dichloro-methane disolvate

摘要

著录项

相似文献

相关主题

期刊订阅