A two-dimensional coordination polymer: poly[[bis­[μ2-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ3N:S,S′]cadmium(II)] 3-methyl­pyridine monosolvate]

Arman H.D.; Poplaukhin P.; Tiekink E.R.T.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >A two-dimensional coordination polymer: poly[[bis[μ2-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ3N:S,S′]cadmium(II)] 3-methylpyridine monosolvate]

【24h】

A two-dimensional coordination polymer: poly[[bis[μ2-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ3N:S,S′]cadmium(II)] 3-methylpyridine monosolvate]

机译：二维配位聚合物：[[双[μ2-N-乙基-N-（吡啶-4-基甲基）二硫代氨基甲酸酯-κ3N：S，S']镉（II）] 3-甲基吡啶单溶剂合物]

获取原文

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The title compound, {[Cd(C9H11N2S2)2]·C6H7N}n, features two μ2-κ3-dithiocarbamate ligands each of which chelates one CdII atom, via the S atoms, while simultaneously bridging to another via the pyridyl-N atom. The result is a two-dimensional coordination polymer extending parallel to the ab plane with square channels along the b axis. The CdII atom geometry is based on a distorted cis-N2S4 octahedron. The 3-methylpyridine molecules reside in the channels aligned along the b axis, being held in place by methylene-C—H⋯N(3-methylpyridine) and (3-methylpyridine)-C—H⋯π(pyridyl) interactions. Pyridyl-C—H⋯S and dithiocarbamate-methyl-C—H⋯π(pyridyl) interactions provide connections between layers along the c axis.

机译：标题化合物{[Cd（C9H11N2S2）2] C6H7N} n具有两个μ2-κ3-二硫代氨基甲酸酯配体，每个配体均通过S原子螯合一个CdII原子，同时通过吡啶基-N原子与另一个CdII原子桥接。结果是二维配位聚合物平行于ab平面延伸，沿b轴具有方形通道。 CdII原子的几何形状基于扭曲的顺式N2S4八面体。 3-甲基吡啶分子位于沿b轴排列的通道中，通过亚甲基-CH 3 N（3-甲基吡啶）和（3-甲基吡啶）-CH 3π（吡啶基）相互作用保持在适当位置。吡啶基-C⋯S和二硫代氨基甲酸酯-甲基-C⋯π（吡啶基）相互作用提供了沿c轴的层间连接。

著录项

来源
《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第4期|共5页
作者
Arman H.D.; Poplaukhin P.; Tiekink E.R.T.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种
中图分类晶体学;
关键词
CRYSTAL STRUCTURECOORDINATION POLYMERCADMIUMDITHIOCARBAMATEHYDROXYPYRIDINE;

机译：晶体结构配位聚合物二甲基二硫代氨基甲酸羟肟基吡啶;

相似文献

外文文献
中文文献
专利

1. catena-Poly[[bis[2-chloro-6-(1H-1,2,4-triazol-1-yl-κN4)pyridine]cadmium(II)]-di-μ-thiocyanato-κ2N:S;κ2S:N]: a one-dimensional coordination polymer [J] . Sun T.T., Yang Z.N. Acta Crystallographica Section E: Crystallographic Communications . 2008,第10期

机译：阳离子聚[[双[2-氯-6-（1H-1,2,4-三唑-1-基-κN4）吡啶]镉（II）]-二-μ-硫氰酸根-κ2N：S;κ2S： N]：一维配位聚合物
2. catena-Poly[[bis[2-chloro-6-(1H-1,2,4-triazol-1-yl-κN4)pyridine]cadmium(II)]-di-μ-thiocyanato-κ2N:S;κ2S:N]: a one-dimensional coordination polymer [J] . Sun T.T., Yang Z.N. Acta Crystallographica Section E: Crystallographic Communications . 2008,第10期

机译：阳离子聚[[双[2-氯-6-（1H-1,2,4-三唑-1-基-κN4）吡啶]镉（II）]-二-μ-硫氰酸根-κ2N：S;κ2S： N]：一维配位聚合物
3. Crystal structure of a CoII coordination polymer with a dipyridyl ligand: catena-poly[[bis(nitrato-κ2O,O′)cobalt(II)]-μ-N-(pyridin-2-ylmethyl)pyridine-3-amine-κ3N,N′:N′′] [J] . Moon S.-H., Kang Y., Park K.-M. Acta Crystallographica Section E: Crystallographic Communications . 2017,第11期

机译：具有二吡啶基配体的CoII配位聚合物的晶体结构：链状聚[[双（nitrato-κ2O，O'）钴（II）]-μ-N-（吡啶-2-基甲基）吡啶-3-胺-κ3N ，N'：N'']
4. A two-dimensional coordination polymer: polybisμ2-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ3N:SS′cadmium(II) 3-methylpyridine monosolvate [O] . Hadi D. Arman, Pavel Poplaukhin, Edward R. T. Tiekink 2017

机译：二维配位聚合物：聚双 μ2-N-乙基-N-（吡啶-4-基甲基基）二硫代氨基甲酸-κ3N：SS镉（II） 3-甲基吡啶单溶剂化物
5. A two-dimensional coordination polymer: poly[[bis[μ2-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ3N:S,S′]cadmium(II)] 3-methylpyridine monosolvate] [O] . Hadi D. Arman, Pavel Poplaukhin, Edward R. T. Tiekink 2017

机译：二维配位聚合物：聚[[双[μ2-N-乙基-N-（吡啶-4-基甲基）二硫代氨基甲酸-κ3N：s，s']镉（II）] 3-甲基吡啶单溶剂化物]

A two-dimensional coordination polymer: poly[[bis­[μ2-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ3N:S,S′]cadmium(II)] 3-methyl­pyridine monosolvate]

摘要

著录项

相似文献

相关主题

期刊订阅

A two-dimensional coordination polymer: poly[[bis[μ2-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ3N:S,S′]cadmium(II)] 3-methylpyridine monosolvate]