Crystal structure of calcium dinickel(II) iron(III) tris-(orthophosphate): CaNi2Fe(PO4)3

Ouaatta S.; Assani A.; Saadi M.; El Ammari L.

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Crystal structure of calcium dinickel(II) iron(III) tris-(orthophosphate): CaNi2Fe(PO4)3

机译：三（正磷酸）钙二镍（II）铁（III）的晶体结构：CaNi2Fe（PO4）3

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The title compound, CaNi2Fe(PO4)3, was synthesized by solid-state reactions. Its structure is closely related to that of α-CrPO4 in the space group Imma. Except for two O atoms in general positions, all atoms are located in special positions. The three-dimensional framework is built up from two types of sheets extending parallel to (100). The first sheet is made up from two edge-sharing [NiO6] octa-hedra, leading to the formation of [Ni2O10] double octa-hedra that are connected to two PO4 tetra-hedra through a common edge and corners. The second sheet results from rows of corner-sharing [FeO6] octa-hedra and PO4 tetra-hedra forming an infinite linear chain. These layers are linked together through common corners of PO4 tetra-hedra and [FeO6] octa-hedra, resulting in an open three-dimensional framework that delimits two types of channels parallel to [100] and [010] in which the eightfold-coordinated CaII cations are located.

机译：通过固相反应合成标题化合物CaNi2Fe（PO4）3。其结构与空间群Imma中的α-CrPO4密切相关。除了两个O原子位于一般位置外，所有原子都位于特殊位置。三维框架由平行于（100）延伸的两种类型的图纸构建而成。第一层由两个边缘共享的[NiO6]八面体组成，导致形成[Ni2O10]双八面体，它们通过一个公共边和角与两个PO4四面体相连。第二张纸是由排成一角的[FeO6]八面体和PO4四面体形成无限的线性链而产生的。这些层通过PO4四面体和[FeO6]八面体的公共角链接在一起，从而形成一个开放的三维框架，该框架界定了与[100]和[010]平行的两种通道，其中八倍坐标CaII阳离子位于。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第6期|共3页
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Ouaatta S.; Assani A.; Saadi M.; El Ammari L.;
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1. Crystal structure of calcium dinickel(II) iron(III) tris-(orthophosphate): CaNi2Fe(PO4)3 [J] . Ouaatta S., Assani A., Saadi M., Acta Crystallographica Section E: Crystallographic Communications . 2017,第6期

机译：三（正磷酸）钙二镍（II）铁（III）的晶体结构：CaNi2Fe（PO4）3
2. Synthesis and crystal structure of calcium dizinc iron(III) tris-(orthophosphate), CaZn2Fe(PO4)3 [J] . Khmiyas J., Assani A., Saadi M., Acta Crystallographica Section E: Crystallographic Communications . 2016,第9期

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6. Crystal structure of calcium dinickel(II) iron(III) tris(orthophosphate): CaNi2Fe(PO4)3 [O] . Said Ouaatta, Abderrazzak Assani, Mohamed Saadi, 2017

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7. Crystal structure of calcium dinickel(II) iron(III) tris(orthophosphate): CaNi2Fe(PO4)3 [O] . Said Ouaatta, Abderrazzak Assani, Mohamed Saadi, 2017

机译：二镍（II）铁（III）三（正磷酸盐）的晶体结构：CaNi2Fe（pO4）3

Crystal structure of calcium dinickel(II) iron(III) tris-(orthophosphate): CaNi2Fe(PO4)3

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