Crystal structure of bis­[4′-(1,4,7,10-tetra­oxa-13- aza­cyclo­penta­decan-13-yl)-2,2′:6′,2′′-terpyridine]­cobalt(III) tris­(perchlorate) methanol monosolvate monohydrate

Ohmagari H.; Nakaya M.; Ohtani R.; Nakamura M.; Hayami S.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of bis[4′-(1,4,7,10-tetraoxa-13- azacyclopentadecan-13-yl)-2,2′:6′,2′′-terpyridine]cobalt(III) tris(perchlorate) methanol monosolvate monohydrate

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Crystal structure of bis[4′-(1,4,7,10-tetraoxa-13- azacyclopentadecan-13-yl)-2,2′:6′,2′′-terpyridine]cobalt(III) tris(perchlorate) methanol monosolvate monohydrate

机译：双[4'-（1,4,7,10-四氧杂十三-氮杂环戊二烯-13-基）-2,2'：6'，2''-吡啶吡啶]三（高氯酸盐）钴（III）的晶体结构一水合甲醇一水合物

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In the title compound, [Co(C25H30N4O4)2](ClO4)3·CH3OH·H2O, the metal atom is coordinated by two tridentate crown ether terpyridine ligands, forming a distorted CoN6 octahedron. The three pyridine rings in each crown–terpyridine ligand are approximately coplanar [maximum deviations = 0.088 (12) and 0.102 (15) Å] and the mean planes through the three pyridine rings are perpendicular to each other, making a dihedral angle of 89.95 (17)°. An intramolecular C—H⋯π interaction is observed between the two terpyridine ligands. In the crystal, O—H⋯O and C—H⋯O hydrogen bonds, a π–π stacking interaction [centroid–centroid distance = 3.923 (7) Å] and a C—H⋯π interaction connect the complex cation, the perchlorate anions and the two types of solvent molecules, forming a three-dimensional network.

机译：在标题化合物[Co（C25H30N4O4）2]（ClO4）3·CH3OH·H2O中，金属原子由两个三齿冠醚叔吡啶配体配位，形成扭曲的CoN6八面体。每个冠-吡啶吡啶配体中的三个吡啶环近似共面[最大偏差= 0.088（12）和0.102（15）Å]，并且穿过三个吡啶环的平均平面彼此垂直，二面角为89.95（ 17）°。在两个三联吡啶配体之间观察到分子内CH键的相互作用。在晶体中，OH-O和CHOH氢键，π-π堆积相互作用[质心-质心距离= 3.923（7）Å]和CH-π相互作用连接了复杂的阳离子，高氯酸根阴离子和两种类型的溶剂分子，形成三维网络。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2015年第8期|共3页
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Ohmagari H.; Nakaya M.; Ohtani R.; Nakamura M.; Hayami S.;
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中图分类晶体学;
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CRYSTAL STRUCTURETERPYRIDINECROWN ETHERHYDROGEN BONDINGC-H...PI INTERACTIONSPI-PI STACKING INTERACTIONS;

机译：晶体结构吡啶衍生物氢键C-H ... [PI]相互作用[PI]-[PI]堆积相互作用;

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2. Crystal structures of the water and acetone monosolvates of bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate) [J] . Louren#231, o L.M.O., Almeida Paz F.A., Acta Crystallographica Section E: Crystallographic Communications . 2015,第4期

机译：双[6'-（吡啶-4-基）-2,2'：6'，2''-吡啶吡啶]锰（II）双（六氟磷酸）的水和丙酮单溶剂化物的晶体结构
3. Crystal structure of bis{μ2-2,2′-[(4,10-dimethyl-1,4,7,10-tetraazacyclododecane-1,7-diyl)bis(methylene)]bis(4-oxo-4H-pyran-3-olato)}dicobaltcalcium bis(perchlorate) 1.36-hydrate [J] . Rossi P., Macedi E., Paoli P., Acta Crystallographica Section E: Crystallographic Communications . 2017,第12期

机译：双{μ2-2,2'-[（4,10-二甲基-1,4,7,10-四氮杂环十二烷-1,7-二基）双（亚甲基）]双（4-氧代-4H-吡喃）的晶体结构-3-olato）}二钴双（高氯酸盐）钙1.36水合物
4. Crystal structure of bis4′-(14710-tetraoxa-13- azacyclopentadecan-13-yl)-22′:6′2′′-terpyridinecobalt(III) tris(perchlorate) methanol monosolvate monohydrate [O] . Hitomi Ohmagari, Manabu Nakaya, Ryo Ohtani, 2015

机译：双4-（14710-四氧杂十三-氮杂环十五烷-13-基）-22：62-吡啶吡啶三（高氯酸盐）钴（III）的晶体结构一水合甲醇一水合物
5. Crystal structure of bis[4′-(1,4,7,10-tetraoxa-13- azacyclopentadecan-13-yl)-2,2′:6′,2′′-terpyridine]cobalt(III) tris(perchlorate) methanol monosolvate monohydrate [O] . Hitomi Ohmagari, Manabu Nakaya, Ryo Ohtani, 2015

机译：双[4' - （1,4,7,10-四氧杂-13-氮杂环十五烷-13-基）-2,2'：6'，2'-三联吡啶]钴（III）三（高氯酸盐）的晶体结构甲醇单溶剂化一水合物

Crystal structure of bis­[4′-(1,4,7,10-tetra­oxa-13- aza­cyclo­penta­decan-13-yl)-2,2′:6′,2′′-terpyridine]­cobalt(III) tris­(perchlorate) methanol monosolvate monohydrate

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Crystal structure of bis[4′-(1,4,7,10-tetraoxa-13- azacyclopentadecan-13-yl)-2,2′:6′,2′′-terpyridine]cobalt(III) tris(perchlorate) methanol monosolvate monohydrate