Crystal structure of (E)-4-{1-[2-(car­bamo­thio­yl)hydrazin-1-yl­idene]ethyl}phenyl 4-methyl­benzoate

Mani K.A.; Viswanathan V.; Narasimhan S.; Velmurugan D.

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Crystal structure of (E)-4-{1-[2-(carbamothioyl)hydrazin-1-ylidene]ethyl}phenyl 4-methylbenzoate

机译：（E）-4- {1- [2- [氨基甲硫酰基）肼-1-亚甲基]乙基} 4-甲基苯甲酸苯基酯的晶体结构

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摘要

The asymmetric unit of the title compound, C17H17N3O2S, consists of two independent molecules, A and B, with different conformations: in molecule A, the dihedral angles between the central benzene ring and the pendant tolyl and carbamothioylhydrazono groups are 71.12 (9) and 5.95 (8)°, respectively. The corresponding angles in molecule B are 50.56 (12) and 26.43 (11)°, respectively. Both molecules feature an intramolecular N—H⋯N hydrogen bond, which closes an S(5) ring. In the crystal, molecules are linked by N—H⋯O, N—H⋯S and C—H⋯O hydrogen bonds, generating a three-dimensional network.

机译：标题化合物C17H17N3O2S的不对称单元由两个独立的分子A和B组成，它们具有不同的构象：在分子A中，中心苯环与悬挂的甲苯基和氨基甲硫酰基肼基之间的二面角为71.12（9）和5.95。分别为（8）°。分子B中相应的角度分别为50.56°（12）和26.43°（11）°。这两个分子均具有一个分子内N–H hydrogenN氢键，该氢键闭合S（5）环。在晶体中，分子通过NH⋯O，NH⋯S和CH hydrogenO氢键连接，生成三维网络。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2015年第1期|共页
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Mani K.A.; Viswanathan V.; Narasimhan S.; Velmurugan D.;
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中图分类晶体学;
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CRYSTAL STRUCTURETHIOSEMICARBAZONES DERIVATIVESBIOLOGICAL ACTIVITYHYDROGEN BONDINGESTER;

机译：晶体结构硫代咪唑衍生物生物学活性氢键键合酯;

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Crystal structure of (E)-4-{1-[2-(car­bamo­thio­yl)hydrazin-1-yl­idene]ethyl}phenyl 4-methyl­benzoate

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Crystal structure of (E)-4-{1-[2-(carbamothioyl)hydrazin-1-ylidene]ethyl}phenyl 4-methylbenzoate