Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabi­cyclo­[3.2.1]oct-3-yl)ammonium aqua­tri­chlorido­nitratocopper(II)

Britvin S.N.; Rumyantsev A.M.

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Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabicyclo[3.2.1]oct-3-yl)ammonium aquatrichloridonitratocopper(II)

机译：（1R，5S）-endo-（8-methyl-8-azoniabicyclo [3.2.1] oct-3-yl）amquatrichloridonitratocopper（II）的晶体结构

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The structure of a salt of diprotonated endo-3-aminotropane crystallized with a copper(II) anionic cluster is reported, viz. (C8H18N2)[CuCl3(NO3)(H2O)]. Neither ion in the salt has been structurally characterized previously. In the crystal, the ions pack together to form a three-dimensional structure held together by a network of intermolecular N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen-bonding interactions. Selective crystallization of the title compound can be considered as a simple method for the separation of the exo and endo isomers of 3-aminotropane.

机译：报道了用铜（II）阴离子簇结晶的二质子化的3-氨基苯甲酸内酯的盐的结构，即。（C8H18N2）[CuCl3（NO3）（H2O）]。盐中的两个离子先前都没有在结构上进行过表征。在晶体中，离子堆积在一起形成三维结构，这些三维结构通过分子间N-H，O，OH-Cl和N-H⋯Cl氢键相互作用的网络保持在一起。标题化合物的选择性结晶可以被认为是分离3-氨基环烷的外向异构体和内向异构体的简单方法。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第11期|共4页
作者
Britvin S.N.; Rumyantsev A.M.;
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中图分类晶体学;
关键词
CRYSTAL STRUCTURETROPANENITROGEN HETEROCYCLECOPPER(II)COMPLEXISOMER SEPARATION;

机译：晶体结构泛氮杂环铜（II）复合异构体的分离;

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1. Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabicyclo[3.2.1]oct-3-yl)ammonium aquatrichloridonitratocopper(II) [J] . Britvin S.N., Rumyantsev A.M. Acta Crystallographica Section E: Crystallographic Communications . 2017,第11期

机译：（1R，5S）-endo-（8-methyl-8-azoniabicyclo [3.2.1] oct-3-yl）amquatrichloridonitratocopper（II）的晶体结构
2. Crystal structures of diiodidobis[(1S,5S)-4-mesityl-1,2,8,8-tetramethyl-2,4-diazabicyclo[3.2.1]octan-3-ylidene-κC3]palladium(IV) and dichlorido[(1S,5S)-4-mesityl-1,2,8,8-tetramethyl-2,4-diazabicyclo[3.2.1]octan-3-ylidene-κC3](triphenylphosphane-κP)palladium(IV) [J] . Rais E., Fl#246, rke U., Acta Crystallographica Section E: Crystallographic Communications . 2015,第8期

机译：二碘双（[（1S，5S）-4-mesityl-1,2,8,8-四甲基-2,4-二氮杂双环[3.2.1]辛基-3-亚烷基-κC3]钯（IV）和双氯碘的晶体结构。（1S，5S）-4-间苯甲基-1,1,2,8,8-四甲基-2,4-二氮杂双环[3.2.1]辛-3-亚烷基-κC3]（三苯基膦-κP）钯（IV）
3. Crystal structure of μ-1κC:2(η2)-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chloridoborylene-1:2κ2B:B-[1(η5)-pentamethylcyclopentadienyl](tricyclohexylphosphane-2κP)iron(II)platinum(II) benzene monosolvate [J] . Braunschweig H., Kramer T. Acta Crystallographica Section E: Crystallographic Communications . 2014,第11期

机译：μ-1κC：2（η2）-羰基-羰基-1κC-氯基-2κCl-μ-氯代甲硼烷-1：2κ2B：B- [1（η5）-五甲基环戊二烯基]（三环己基膦-2κP）铁（II）的晶体结构（II）苯单溶剂化物
4. Synthesis,Crystal structure and DNA Binding of of a chiral new Cu(II) complex with (1R, 2R)-1,2-hexanediamine [C] . Yinzhi Jiang, Zhenyu Chen, Liangqun Zhang MEMC 2013 . 2013

机译：对（1R，2R）-1,2-己二胺的手性新Cu（II）复合物的合成，晶体结构和DNA结合
5. Design and synthesis of organic chiroptical switches: Part I. Improvement of the chiroptical liquid crystal switch by modifying the structure of [3.2.1]bicyclooctanone. Part II. Design and synthesis of photoresponsive polyisocyanates. [D] . Li, Jie. 1999

机译：有机手性开关的设计和合成：第一部分，通过修改[3.2.1]双环辛酮的结构来改进手性液晶开关。第二部分设计和合成光响应性多异氰酸酯。
6. Crystal structure of (1R5S)-endo-(8-methyl-8-azoniabicyclo3.2.1oct-3-yl)ammonium aquatrichloridonitratocopper(II) [O] . Sergey N. Britvin, Andrey M. Rumyantsev 2017

机译：（1R5S）-内-（8-甲基-8-氮杂双环 3.2.1辛-3-基）水合三氯代硝基铜的晶体结构（II）
7. Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabicyclo[3.2.1]oct-3-yl)ammonium aquatrichloridonitratocopper(II) [O] . Sergey N. Britvin, Andrey M. Rumyantsev 2017

机译：（1R，5s） - 内 - （8-甲基-8-氮杂双环[3.2.1]辛-3-基）铵水杨醛硝酸铜（II）的晶体结构

Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabi­cyclo­[3.2.1]oct-3-yl)ammonium aqua­tri­chlorido­nitratocopper(II)

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Crystal structure of (1R,5S)-endo-(8-methyl-8-azoniabicyclo[3.2.1]oct-3-yl)ammonium aquatrichloridonitratocopper(II)