Effects of Co/Ce molar ratio and operating temperature on nanocatalyst performance in the Fischer–Tropsch synthesis

Tahereh Taherzadeh Lari; Ali Akbar Mirzaei; Hossein Atashi

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Effects of Co/Ce molar ratio and operating temperature on nanocatalyst performance in the Fischer–Tropsch synthesis

机译：费-托合成中Co / Ce摩尔比和操作温度对纳米催化剂性能的影响

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Iron–cobalt–cerium three-metal nanoparticles have been obtained by a solvothermal method for converting synthesis gas into light olefins. The effect of various fabrication molar ratios of Co/Ce and the effect of the operating temperature (270–400 °C) on the activity and selectivity were demonstrated. The nanocatalyst with a 1?:?1/4 Co/Ce molar ratio at an operating temperature of 300 °C performed optimally in selectivity converting synthesis gas into light olefin. The nanocatalysts prepared with different Co/Ce molar ratios were characterized. The morphology, structure and magnetic behavior were established by SEM, EDX, FTIR, XRD and VSM *techniques.

机译：铁-钴-铈三金属纳米粒子是通过溶剂热法将合成气转化为轻质烯烃而获得的。证明了各种制造摩尔比Co / Ce的影响以及操作温度（270-400°C）对活性和选择性的影响。在300℃的操作温度下，具有1∶∶1 / 4Co / Ce摩尔比的纳米催化剂在将合成气转化为轻质烯烃的选择性方面表现最佳。表征了以不同的Co / Ce摩尔比制备的纳米催化剂。通过SEM，EDX，FTIR，XRD和VSM技术建立了形貌，结构和磁行为。

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《RSC Advances》 |2017年第55期|共11页
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Tahereh Taherzadeh Lari; Ali Akbar Mirzaei; Hossein Atashi;
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1. Effects of Co/Ce molar ratio and operating temperature on nanocatalyst performance in the Fischer–Tropsch synthesis [J] . Tahereh Taherzadeh Lari, Ali Akbar Mirzaei, Hossein Atashi RSC Advances . 2017,第55期

机译：费-托合成中Co / Ce摩尔比和操作温度对纳米催化剂性能的影响
2. Fischer-Tropsch synthesis over an iron-cobalt-manganese (ternary) nanocatalyst prepared by hydrothermal procedure: Effects of nanocatalyst composition and operational conditions [J] . Golestan Somayeh, Mirzaei Ali Akbar, Atashi Hossein International journal of hydrogen energy . 2017,第15期

机译：水热法制备的铁钴锰（三元）纳米催化剂上的费-托合成：纳米催化剂组成和操作条件的影响
3. Inorganic complex precursor route for preparation of high-temperature Fischer-Tropsch synthesis Ni-Co nanocatalysts [J] . Farzanfar Javad, Rezvani Ali Reza Research on Chemical Intermediates . 2015,第11期

机译：无机配合物前体路线制备高温费-托合成Ni-Co纳米催化剂
4. Effects of Cu and K promoters on the catalytic performance of iron- based nanocatalyst for Fischer-Tropsch synthesis [C] . Sara Faiz Hanna Tasfy, Noor Asmawati Mohd Zabidi, Duvvuri Subbarao International Conference on Nanoscience Nanotechnology . 2014

机译：Cu和K启动子对铁蝇合成铁基纳米催化剂催化性能的影响
5. Effect of Promoter (Mn) on the Performance of SBA-15 Supported Iron Catalysts forHigh Temperature Fischer-Tropsch Synthesis [D] . Seby, Sreya Mariya. 2019

机译：启动子（Mn）对高温Fischer-Tropsch合成的SBA-15负载铁催化剂性能的影响
6. Effects of the Functionalization of the Ordered Mesoporous Carbon Support Surface on Iron Catalysts for the Fischer–Tropsch Synthesis of Lower Olefins [O] . Dr. Martin Oschatz, Dr. Jan P. Hofmann, Tom W. van Deelen, -1

机译：有序介孔碳载体表面功能化对铁催化剂费-托合成低级烯烃的影响
7. Effects of Cu and K promoters on the catalytic performance of iron- based nanocatalyst for Fischer-Tropsch synthesis [O] . Sara Faiz, Hanna Tasfy, Noor Asmawati, 2016

机译：Cu和K助剂对铁基纳米催化剂对费 - 托合成催化性能的影响
8. Performance Testing with a Gas-Liquid-Solid System in a Mechanically-Stirred Reactor: The Fischer-Tropsch Synthesis. [R] . Donnelly, T. J., Satterfield, C. N. 1987

机译：在机械搅拌反应器中使用气液固体系进行性能测试：Fischer-Tropsch合成。

Effects of Co/Ce molar ratio and operating temperature on nanocatalyst performance in the Fischer–Tropsch synthesis

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