Versatile magnetic resonance singlet tags compatible with biological conditions

Stefan Gl?ggler; Stuart J. Elliott; Gabriele Stevanato; Richard C. D. Brown; Malcolm H. Levitt

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Versatile magnetic resonance singlet tags compatible with biological conditions

机译：多功能磁共振单峰标签与生物学条件兼容

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The long lifetime of nuclear singlet states holds promise for the development of molecular tracers to study motional processes in proteins with increased precision or to act as imaging contrast agents. We introduce a singlet tag (STAG) based on bromoacrylate that is readily attached to a variety of biomolecules, compatible with biological conditions, and is relatively insensitive to the presence of molecular oxygen. The generality of this approach is demonstrated by tagging buildings blocks for biomolecules using a simple labelling route based on commercially available starting materials. Additionally, we demonstrate a singlet NMR experiment on the endogenous molecule phosphoenolpyruvate.

机译：核单重态的长寿命为分子示踪剂的发展提供了希望，以研究蛋白质中的运动过程，并提高精确度或充当成像造影剂。我们介绍了一种基于溴丙烯酸酯的单峰标签（STAG），该标签易于附着到各种生物分子上，与生物学条件兼容，并且对分子氧的存在相对不敏感。这种方法的普遍性通过使用基于市售起始材料的简单标记途径标记生物分子的结构单元来证明。此外，我们证明了内源性分子磷酸烯醇丙酮酸的单线核磁共振实验。

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《RSC Advances》 |2017年第55期|共5页
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Stefan Gl?ggler; Stuart J. Elliott; Gabriele Stevanato; Richard C. D. Brown; Malcolm H. Levitt;
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机译：功能性磁共振成像（fMRI）中的屈光异常和视觉激活：一种多功能且低成本的MR兼容设备，可纠正潜在的混淆。
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机译：铁蛋白腔中β-MnOOH纳米相的还原/溶解可产生高灵敏度，生物相容的磁共振成像剂†
3. Reduction/Dissolution of a β-MnOOH Nanophase in the Ferritin Cavity To Yield a Highly Sensitive, Biologically Compatible Magnetic Resonance Imaging Agent† [J] . li id=au1Ferenc#x2005, Krisztián Kálmán Dr. li id=au2Simonetta Geninatti-Crich Dr. li id=au3Silvio Aime Prof. Angewandte Chemie International Edition . 2010,第3期

机译：铁蛋白腔中β-MnOOH纳米相的还原/溶解可产生高灵敏度，生物相容的磁共振成像剂†
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机译：生物相容性g（at）（碳纳米结构）作为磁共振成像的高级造影剂。
6. Development of a hybrid magnetic resonance/computed tomography-compatible phantom for magnetic resonance guided radiotherapy [O] . Min-Joo Kim, Seu-Ran Lee, Kyu-Ho Song, 2020

机译：磁共振/放射线断层扫描兼容体模的开发用于磁共振引导放射治疗
7. Versatile magnetic resonance singlet tags compatible with biological conditions. [O] . Glöggler, S., Elliott, S., Stevanato, G., 2017

机译：多功能磁共振单线标签兼容生物条件。
8. Versatile Pulse Programmer for Pulsed Nuclear Magnetic Resonance Spectroscopy [R] . Adduci, D. J. 1979

机译：用于脉冲核磁共振光谱的通用脉冲编程器

Versatile magnetic resonance singlet tags compatible with biological conditions

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