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Tunable multilayer assemblies of nanofibrous composite mats as permeable protective materials against chemical warfare agents

机译:纳米纤维复合垫的可调谐多层组件,作为抗化学战剂的可渗透保护材料

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Lightweight nanofibrous assemblies with high protection ability against chemical warfare agents (CWAs) were developed using laminated outer and inner layers based on nanofibre composites. The outer layer was composed of a meta-aramid nanofibre and CWA adsorbents (MgO and POM), and possessed high mechanical strength and an amphiphobic surface capable of repelling liquid CWAs. The inner layer, consisted of a polyamide 66 nanofibre and CWA adsorbents, exhibited low permeability to gas CWAs and high permeability to water vapor. These outer and inner layers were prepared by simultaneous electrospinning and electrospraying processes. By controlling the stacking of the inner and outer layers, the characteristics of their assemblies, such as thickness, weight density, and cool/warm feeling, were improved. In addition, the assemblies resisted the invasion of CWAs, while still maintaining considerable water vapor transmission to allow evaporative cooling of the wearer. Based on these results, assemblies composed of nanofibrous composite can be used as in garments that protect wearers from various contaminants such as organic pollutants and harmful particulates, as well as from CWAs.
机译:使用基于纳米纤维复合材料的层压内外层,开发了具有高抗化学战剂(CWA)保护能力的轻量级纳米纤维组件。外层由 met -芳族聚酰胺纳米纤维和CWA吸附剂(MgO和POM)组成,具有高机械强度和能够排斥液体CWA的两性表面。内层由聚酰胺66纳米纤维和CWA吸附剂组成,对气体CWA的渗透性低,对水蒸气的渗透性高。这些外层和内层是通过同时电纺丝和电喷涂工艺制备的。通过控制内层和外层的堆叠,改善了它们的组件的特性,例如厚度,重量密度和凉爽/温暖的感觉。另外,这些组件抵抗了CWA的入侵,同时仍保持了相当大的水蒸气传输能力,从而使穿着者得以蒸发冷却。基于这些结果,由纳米纤维复合材料制成的组件可用于服装中,以保护穿着者免受各种污染物(例如有机污染物和有害颗粒)以及CWA的侵害。

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