Intra- and intermolecular interaction of anthracene moieties in 7,8-disilabicyclo[3.3.0]octadienyl-bridged bisanthracenes

Yuichiro Tokoro; Nobuhiko Ohtsuka; Shin-ichi Fukuzawa; Toshiyuki Oyama

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Intra- and intermolecular interaction of anthracene moieties in 7,8-disilabicyclo[3.3.0]octadienyl-bridged bisanthracenes

机译：7,8-二硅双环[3.3.0]辛二烯基-桥联双蒽中蒽部分的分子内和分子间相互作用

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Ruthenium-catalyzed dimerization of 9-anthrylarylsilanes afforded air-stable V-shaped bisanthracenes bridged by a 7,8-disilabicyclo[3.3.0]octadiene moiety. The intra- and intermolecular proximity of the anthracene moieties were determined by single-crystal X-ray analysis. Absorption and emission maxima of the disilabicyclo[3.3.0]octadienyl-bridged bisanthracenes in the solution state were observed at longer wavelengths than those of 9-anthryldimethylsilane and bis(9-anthryl)dimethylsilane. The V-shaped bisacenes in the solid state showed excimer emissions with moderate quantum yields.

机译：钌催化的9-蒽芳基硅烷的二聚反应提供了由7,8-二硅双环[3.3.0]辛二烯部分桥接的空气稳定的V形双蒽。蒽部分的分子内和分子间接近度通过单晶X射线分析确定。在比9-蒽基二甲基硅烷和双（9-蒽基）二甲基硅烷更长的波长处，观察到在溶液状态下双二环[3.3.0]辛二烯基-桥联的双蒽的吸收和发射最大值。固态的V形双并二苯具有准分子发射，量子产率中等。

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《RSC Advances》 |2018年第44期|共4页
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Yuichiro Tokoro; Nobuhiko Ohtsuka; Shin-ichi Fukuzawa; Toshiyuki Oyama;
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1. Intra- and intermolecular interaction of anthracene moieties in 7,8-disilabicyclo[3.3.0]octadienyl-bridged bisanthracenes [J] . Tokoro Yuichiro, Ohtsuka Nobuhiko, Fukuzawa Shin-Ichi, RSC Advances . 2018,第44期

机译：蒽部分在7,8-二硅酰亚胺中的分子间和分子间相互作用[3.3.0]八炔基 - 桥接的小苯妥
2. Intra- and intermolecular interaction of anthracene moieties in 7,8-disilabicyclo[3.3.0]octadienyl-bridged bisanthracenes [J] . Yuichiro Tokoro, Nobuhiko Ohtsuka, Shin-ichi Fukuzawa, RSC Advances . 2018,第44期

机译：7,8-二硅双环[3.3.0]辛二烯基-桥联双蒽中蒽部分的分子内和分子间相互作用
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4. Rewritable Photopatterning of a Bisanthracene-Functionalized Mesogenic Compound by Photodimerization and Thermal Back-Reaction of the Anthracene Moiety [C] . Hideyuki Kihara, Masashi Motohashi, Kazunari Matsumua, MRS fall meeting . 2012

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5. The Arabidopsis CRINKLY4 receptor-like kinase and homologs: Regulation of kinase activity through intra- and intermolecular interactions. [D] . Meyer, Matthew Richard. 2012

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7. Intra- and intermolecular interaction of anthracene moieties in 7,8-disilabicyclo3.3.0octadienyl-bridged bisanthracenes [O] . Yuichiro Tokoro, Nobuhiko Ohtsuka, Shin-ichi Fukuzawa, 2018

机译：蒽部分在7,8-二硅酰亚胺中的分子间和分子间相互作用3.3.0八炔基 - 桥接的小苯妥

Intra- and intermolecular interaction of anthracene moieties in 7,8-disilabicyclo[3.3.0]octadienyl-bridged bisanthracenes

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