• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>RSC Advances >Ag+, Fe3+ and Zn2+-intercalated cadmium(II)-metal–organic frameworks for enhanced daylight photocatalysis
【24h】

Ag+, Fe3+ and Zn2+-intercalated cadmium(II)-metal–organic frameworks for enhanced daylight photocatalysis

机译：Ag + ，Fe 3 + 和Zn 2 + 嵌入的镉（II）-金属-有机骨架增强了日光催化

获取原文
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Design and synthesis of multi-dimensional metal–organic frameworks are fascinating because MOFs possess intriguing structures and unique properties and exhibit potential applications in photocatalysis. In the present study, we endeavoured to synthesize a new Cd-linked MOF through a simple hydrothermal route. The daylight utilising attributes of the Cd-MOF were enhanced by intercalating Ag+, Fe3+, and Zn2+ into the framework via an ion-exchange technique. The optical property shows that Fe3+ stimulates the photo response in the visible region, whereas Ag+ and Zn2+ stimulate the photo response in the ultraviolet light region. Photocatalytic efficiency of the developed MOFs was investigated by degradation of 2-CP under daylight illumination. The Cd-MOFs intercalated with Fe3+ exhibit excellent photocatalysis as compared to the rest, degrading 93% of 2-CP in 5 h of illumination. The intercalation of Fe3+ onto the Cd-MOF significantly reduced the energy gap of the pure MOF; this led to an increased formation of reactive oxygen species driven by the electrons (e?) and holes (h+). Thus, the developed modified MOF clearly demonstrated its capability as a daylight photocatalyst as compared to the existing conventional photocatalysts.
机译：多维金属有机框架的设计和合成引人入胜，因为MOF具有引人入胜的结构和独特的性能，并在光催化领域具有潜在的应用。在本研究中，我们努力通过简单的水热途径合成新的Cd连接的MOF。通过插入Ag + ，Fe 3 + 和Zn增强Cd-MOF的日光利用属性通过离子交换技术将 2 + 放入框架。光学性质表明，Fe 3 + 刺激可见光区域的光响应，而Ag + 和Zn 2 + 刺激紫外线区域的光响应。通过在日光下降解2-CP来研究已开发MOF的光催化效率。嵌入Fe 3 + 的Cd-MOFs与其余的相比表现出优异的光催化作用，在光照5小时内降解了2-CP的93％。 Fe 3 + 插在Cd-MOF上可显着减小纯MOF的能隙。这导致由电子（e ？ ）和空穴（h + ）。因此，与现有的常规光催化剂相比，开发的改性MOF清楚地证明了其作为日光光催化剂的能力。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号