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High rate performance SnO2 based three-dimensional graphene composite electrode for lithium-ion battery applications

机译:锂离子电池应用的高性能SnO 2 高性能三维石墨烯复合电极

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In order to improve the rate performance and cycling stability at high current densities of lithium-ion batteries (LIBs), a sample composite of SnO2 and three-dimensional graphene (SnO2/3DG) was fabricated using a hydrothermal method, with polystyrene balls (PS) as templates. The reversible capacity is 720.8 mA h g?1 at a current density of 100 mA g?1, after 100 cycles. The rate performance is also excellent, with a reversible capacity of about 800 mA h g?1 at 1000 mA g?1. The excellent electrochemical performance is attributed to its 3D structure, which possesses a large specific surface area and abundant reaction active positions, leading to fast kinetics and short pathways for both Li-ions and electrons.
机译:为了提高锂离子电池(LIBs)在高电流密度下的倍率性能和循环稳定性,SnO 2 和三维石墨烯(SnO)的样品复合物以聚苯乙烯球(PS)为模板,采用水热法制备了 2 / 3DG)。 100后的电流密度为100 mA g ?1 时,可逆容量为720.8 mA hg ?1 周期。速率性能也非常好,在1000 mA g ?1 时可逆容量约为800 mA hg ?1 小>。优异的电化学性能归因于其3D结构,该结构具有大的比表面积和丰富的反应活性位置,从而导致锂离子和电子的快速动力学和短路径。

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