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Robust superhydrophobic and self-lubricating PTES-TiO2@UHMWPE fabric and its tribological properties

机译:耐用的超疏水自润滑PTES-TiO 2 @UHMWPE织物及其摩擦学性能

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A superhydrophobic/self-lubricating fabric with double hierarchical structure was prepared by first etching pristine ultrahigh molecular weight polyethylene (UHMWPE) fibers with air-plasma, followed by a facile in situ growth method. Scanning electron microscopy (SEM) showed that the air-plasma etching treatment generated pits on the fiber surface and TiO2 was grafted onto the etched fiber, which greatly improved its surface roughness. The fabric was further modified by 1H,1H,2H,2H-perfluorodecyltriethoxysilane (PTES), which possesses a low surface free energy. The results showed the PTES-TiO2@UHMWPE fabric possessed superhydrophobic properties with a water contact angle (WCA) of 157.75°, enhanced thermal resistance, and exhibited excellent antiwear properties with a friction coefficient of 0.05. In addition, the PTES-TiO2@UHMWPE fabric retained its superhydrophobicity without an apparent reduction after 30 cycles of washing or 5 minutes of friction treatment, revealing its good mechanical properties. Meanwhile, the mechanical strength of the fabric had little reduction after UV irradiation, which is helpful in enlarging the fabric applications in industry.
机译:首先通过用空气等离子体刻蚀原始的超高分子量聚乙烯(UHMWPE)纤维,然后采用一种简便的原位生长方法,制备出具有双层结构的超疏水/自润滑织物。扫描电子显微镜(SEM)表明,经空气等离子刻蚀处理后,在纤维表面产生了凹坑,并将TiO 2 接枝到被刻蚀的纤维上,极大地改善了其表面粗糙度。 。用1 H ,1 H ,2 H ,2 H -全氟癸基三乙氧基硅烷(PTES)进一步改性,其表面自由能低。结果表明,PTES-TiO 2 @UHMWPE织物具有超疏水性能,水接触角(WCA)为157.75°,耐热性增强,并具有优异的抗磨性能。摩擦系数为0.05。另外,PTES-TiO 2 @UHMWPE织物在洗涤30次或摩擦5分钟后仍保持超疏水性,而没有明显降低,显示出良好的机械性能。同时,紫外线照射后织物的机械强度几乎没有降低,这有助于扩大织物在工业上的应用。

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