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Metallic 1T-TiS2 nanodots anchored on a 2D graphitic C3N4 nanosheet nanostructure with high electron transfer capability for enhanced photocatalytic performance

机译:金属1T-TiS 2 纳米点锚固在具有高电子转移能力的二维石墨C 3 N 4 纳米片纳米结构上,具有增强的光催化性能

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Photocatalysis is one of the most promising technologies for solar energy conversion. With the development of photocatalysis technology, the creation of low-dimensional structure photocatalysts with improved properties becomes more and more important. Metallic 1T-TiS2 nanodots with a low-dimensional structure were introduced into environmentally friendly two-dimensional g-C3N4 (2D-C3N4) nanosheets by a solvothermal method. It was found that the ultrathin TiS2 nanodots were uniformly anchored on the surface of the 2D-C3N4. The effective suppression of electron–hole recombination was realized due to the addition of the intrinsic metallic property of 1T-TiS2 in the prepared nanocomposite. The 5 wt% TiS2/2D-C3N4 nanocomposite exhibited the best photocatalytic performance and the degradation rate towards RhB was ca. 95% in 70 min, which showed an improvement of ca. 30% in comparison with 2D-C3N4. The results indicate that the obtained TiS2/2D-C3N4 nanocomposite is a promising photocatalyst for practical applications.
机译:光催化是最有前途的太阳能转化技术之一。随着光催化技术的发展,具有改进性能的低维结构光催化剂的产生变得越来越重要。将具有低维结构的金属1T-TiS 2 纳米点引入环保二维gC 3 N 4 (2D-C 3 N 4 )通过溶剂热法的纳米片。发现超薄的TiS 2 纳米点均匀地锚固在2D-C 3 N的表面上 4 。通过在制备的纳米复合材料中加入1T-TiS 2 的固有金属性能,实现了有效的电子-空穴复合抑制。 5 wt%TiS 2 / 2D-C 3 N 4 纳米复合材料表现出最佳的光催化性能,在70分钟内对RhB的降解率为 ca。。95%,其中 ca。的降解率为30%。与2D-C 3 N 4 的比较。结果表明获得的TiS 2 / 2D-C 3 N 4 < / sub> 纳米复合材料是一种在实际应用中很有前途的光催化剂。

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