Quantitative detection of H2S and CS2 mixed gases based on UV absorption spectrometry

Xiaoxing Zhang; Zhaolun Cui; Zheng Cheng; Yalong Li; Hai Xiao

首页> 外文期刊>RSC Advances >Quantitative detection of H₂S and CS₂ mixed gases based on UV absorption spectrometry

【24h】

Quantitative detection of H₂S and CS₂ mixed gases based on UV absorption spectrometry

机译：基于紫外吸收光谱法定量检测H _{2 S和CS _{2 混合气体}}

获取原文

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

H₂S and CS₂ are the decomposition components of insulating gas SF₆. The detection of these two gases is significant for the online monitoring and fault diagnosis of SF₆ electrical equipment. In this study, an ultraviolet (UV) differential optical absorption spectrometry (UV-DOAS) platform is established for detecting the concentration of H₂S and CS₂ mixed gases. Based on the platform, we obtained the UV absorption spectra of the two gases. The linear relationship between each gas absorption spectra and the concentration was established by wavelet processing and frequency analysis. The interference between the two gases in the UV spectrum region was studied. H₂S at different concentrations had little effect on the UV absorption spectra of CS₂. The linearity (R2) of CS₂ inversion formula was 0.9997. CS₂ above 50?ppb produces a great interference on H₂S concentration detection. CS₂ concentration has a linear relationship with the H₂S concentration inversion; hence, the H₂S correction formula with CS₂ concentration as the variable is proposed. With the correction formula, the linearity (R2) of H₂S inversion formula reaches 0.9994 in mixed gas detection, which can meet the H₂S and CS₂ mixed gases quantitative detection.

机译：H _{2 S和CS _{2 是绝缘气体SF _{6 。两种气体的检测对于SF _{6 电气设备的在线监测和故障诊断具有重要意义。本研究建立了用于检测H _{2 S和CS 2 混合气体。基于该平台，我们获得了两种气体的紫外吸收光谱。通过小波处理和频率分析建立了各气体吸收光谱与浓度之间的线性关系。研究了紫外光谱区域中两种气体之间的干扰。不同浓度的H _{2 S对CS _{2 的紫外吸收光谱影响很小。 CS _{2 反演公式的线性度（ R 2 ）为0.9997。 CS _{2 高于50？ppb会对H _{2 S浓度检测产生很大的干扰。 CS _{2 浓度与H _{2 S浓度反演具有线性关系。因此，提出了以CS _{2 浓度为变量的H _{2 S校正公式。利用校正公式，H _{2 S的线性度（ R 2 ）混合气体检测中的反演公式达到0.9994，可以满足H _{2 S和CS _{2 混合气体定量的要求检测。}}}}}}}}}}}}}}}}} 展开▼

著录项

来源
《RSC Advances》 |2017年第80期|共10页

作者
Xiaoxing Zhang; Zhaolun Cui; Zheng Cheng; Yalong Li; Hai Xiao;
展开▼

作者单位

展开▼

收录信息

原文格式 PDF

正文语种

中图分类化学;

关键词

相似文献

外文文献

中文文献

专利

1. Quantitative detection of H2S and CS2 mixed gases based on UV absorption spectrometry [J] . Zhang Xiaoxing, Cui Zhaolun, Cheng Zheng, RSC Advances . 2017,第80期

机译：基于UV吸收光谱法的H2S和CS2混合气体的定量检测

2. Quantitative detection of H₂S and CS₂ mixed gases based on UV absorption spectrometry [J] . Xiaoxing Zhang, Zhaolun Cui, Zheng Cheng, RSC Advances . 2017,第80期

机译：基于紫外吸收光谱法定量检测H _{2 S和CS _{2 混合气体}}

3. Quantitative analysis of SO2, H2S and CS2 mixed gases based on ultraviolet differential absorption spectrometry [J] . Cui Zhaolun, Zhang Xiaoxing, Cheng Zheng, Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2019,第期

机译：基于紫外差分吸收光谱法的SO2，H2S和CS2混合气体的定量分析

4. Quantitative Detection of SO2 H2S and CS2 Based on Ultraviolet Absorption Spectrometry and Least Squares Algorithm [C] . Yongtao Chen, Shiling Zhang, Qiang Yao, IEEE Conference on Energy Internet and Energy System Integration . 2020

机译：基于紫外吸收光谱法和最小二乘算法的SO2H2S和CS2的定量检测

5. The signal-to-noise ratio estimation in dispersive absorption spectrometry and new quantitative methods based on the signal-to-noise ratio theory. [D] . Fu, Chifan Thomas. 1998

机译：色散吸收光谱法中的信噪比估算和基于信噪比理论的新定量方法。

6. Ultraviolet Absorption Cross Sections of KOH and KClfor Nonintrusive Species-Specific Quantitative Detection in Hot Flue Gases [O] . Wubin Weng, Christian Brackmann, Tomas Leffler, -1

机译：KOH和KCl的紫外线吸收截面烟气中非侵入性物种特异性定量检测方法

7. Simultaneous Separation and Detection of 18 Phenethylamine/Tryptamine Derivatives by Liquid Chromatography-UV Absorption and -Electrospray Ionization Mass Spectrometry [O] . Yao HSIAO, Ju-Tsung LIU, Cheng-Huang LIN 2009

机译：通过液相色谱 - UV吸收和电气喷雾电离质谱法同时分离和检测18苯甲胺/色氨酸衍生物

1. C20分子与C20-、C202-离子的特性分析与比较 [J] . 张秀梅 ,王利光 ,王志萍 . 原子与分子物理学报 . 2012,第001期

2. 近20年高校学报编辑学者化现状研究——基于20种CSSCI学报84名编辑学术论文的统计 [J] . 徐红萍 . 青岛科技大学学报（社会科学版） . 2020,第002期

3. 华硕首款20英寸16：9 LCD VH202N [J] . . 电子竞技 . 2009,第004期

4. 19寸价钱享受20寸宽屏精彩 VW202T热卖 [J] . . 数码世界 . 2008,第005期

5. 19寸价钱享受20寸宽屏精彩 VW202T热卖 [J] . . 数码世界：A . 2008,第003期

6. 低热中子吸收截面Al20Mo20Nb20V20Zr20高熵合金涂层的制备及表征 [C] . ZHANG Wei ,张伟 ,YANG Ji-jun . 中国核学会2023年学术年会 . 2017

7. 20岁.20人.20年-1980年代20位建筑竞赛获奖者研究 [A] . 杨晓志 . 2018

1. 一种基于ChaCha20和CCSDS的选择性卫星图像压缩加密方法 [P] . 中国专利： CN105704499B . 2018.10.19

2. 一种基于ChaCha20和CCSDS的选择性卫星图像压缩加密方法 [P] . 中国专利： CN105704499A . 2016-06-22

3. Monitoring partial saponification of polyester based fabrics - by measuring the increase in UV absorption of the reagent due to aromatic extracts [P] . 外国专利： FR2498213B1 . 1983-06-10

机译：监测聚酯基织物的部分皂化-通过测量芳香族提取物引起的试剂对紫外线的吸收增加

4. Monitoring partial saponification of polyester based fabrics - by measuring the increase in UV absorption of the reagent due to aromatic extracts [P] . 外国专利： FR2498213A1 . 1982-07-23

机译：监测聚酯基织物的部分皂化-通过测量芳香族提取物引起的试剂对紫外线的吸收增加

5. LOW-POWER MINIATURE LED-BASED UV ABSORPTION DETECTOR WITH LOW DETECTION LIMITS FOR CAPILLARY LIQUID CHROMATOGRAPHY [P] . 外国专利： EP3142765B1 . 2019-08-14

机译：具有低检测限的低功耗微型LED基紫外吸收检测器，用于毛细管液相色谱

相关主题

Quantitative detection of H2S and CS2 mixed gases based on UV absorption spectrometry

摘要

著录项

相似文献

相关主题

期刊订阅

Quantitative detection of H₂S and CS₂ mixed gases based on UV absorption spectrometry