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Polydopamine nanotubes-templated synthesis of TiO2 and its photocatalytic performance under visible light

机译:聚多巴胺纳米管为模板的TiO 2 的合成及其在可见光下的光催化性能

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Herein, we demonstrated that an efficient TiO2 visible-light photocatalyst can be fabricated by templating mesoporous polydopamine (PDA) nanotubes. Because PDA is a nitrogen-doped carbon source, PDA nanotubes as templates elicited distinct advantages for obtained mesoporous TiO2. First, they introduced a codopant of carbon and nitrogen into anatase TiO2 that narrowed its band gap. Second, they could be graphitized in an optimized calcination process to form graphene-like carbon layers on TiO2 surfaces with high conductivity, which assisted the separation of photogenerated electron–holes of TiO2. These features endow TiO2@C-PDA (400-2) excellent photocatalytic performance for the degradation of methyl orange under visible-light irradiation (>420 nm).
机译:在本文中,我们证明了可以通过模板化介孔聚多巴胺(PDA)纳米管来制备有效的TiO 2 可见光光催化剂。由于PDA是一种氮掺杂碳源,因此以PDA纳米管为模板为获得介孔TiO 2 带来了明显的优势。首先,他们将碳和氮的共掺杂物引入到锐钛矿型TiO 2 中,从而缩小了其带隙。其次,可以在优化的煅烧过程中对它们进行石墨化处理,从而在具有高导电性的TiO 2 表面上形成类石墨烯碳层,从而有助于分离光生电子空穴。 TiO 2 。这些特征赋予了TiO 2 @ C-PDA(400-2)优异的光催化性能,在可见光(> 420 nm)下降解甲基橙。

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