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Fabrication of ultralong perovskite structure nanotubes

机译:超长钙钛矿结构纳米管的制备

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Fabrication of high quality nanotubes with thin walls, long length, and uniform diameter is challenging, especially in complex structure oxides, such as perovskites. In this paper, we elucidate a facile method for the preparation of perovskite manganite nanotubes by a sacrificial template assisted pulsed laser deposition technique. Morphological analysis reveals a typical hollow tubular nanostructure of the nanotubes with lengths up to tens of micrometers and the average diameter of 160 nm. The nanotubes are composed of perovskite crystallites with a granular size of 5–10 nm, and show superparamagnetism behavior. The kinetic energy of the plume is crucial for the nanotube formation, which could be tuned by the laser energy density, the pressure of deposition and the target–substrate distance. This sacrificial template method illustrated here does not only propose a universal technique for high quality inorganic nanotube material fabrication, but also provides a promising route to new one-dimensional materials and devices.
机译:具有薄壁,长长度和均匀直径的高质量纳米管的制造是具有挑战性的,特别是在复杂结构的氧化物中,例如钙钛矿。在本文中,我们阐明了一种通过牺牲模板辅助脉冲激光沉积技术制备钙钛矿锰矿纳米管的简便方法。形态分析揭示了纳米管的典型中空管状纳米结构,其长度可达数十微米,平均直径为160 nm。纳米管由钙钛矿微晶组成,晶粒尺寸为5-10 nm,并表现出超顺磁性行为。羽流的动能对于纳米管的形成至关重要,可以通过激光能量密度,沉积压力和目标-基底距离来调节。此处说明的这种牺牲模板方法不仅提出了用于高质量无机纳米管材料制造的通用技术,而且还为开发新型一维材料和器件提供了有希望的途径。

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