Phosphoric acid doped hydrophobic ionic liquid-based composite membranes for anhydrous proton exchange membrane application

Bencai Lin; Gang Qiao; Fuqiang Chu; Shuai Zhang; Ningyi Yuan; Jianning Ding

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Phosphoric acid doped hydrophobic ionic liquid-based composite membranes for anhydrous proton exchange membrane application

机译：磷酸掺杂疏水离子液体基复合膜在无水质子交换膜中的应用

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In this study, phosphoric acid doped hydrophobic ionic liquid-based composite membranes are successfully synthesized and characterized. 1-Vinyl-3-butylimidazolium bis(trifluoromethylsulfonyl)-imide ([VBIm][NTf₂]) was synthesized and used as hydrophobic phase in the composite membranes. The H₃PO₄ uptake of the composite membranes increases with the increasing content of [VBIm][NTf₂] and then decreases. The resultant composite membranes showed good thermal stability, mechanical properties and high proton conductivity (up to the order of 10?2 S cm?1 at 180 °C) at high temperatures under anhydrous conditions. The results of this study suggest that this type of PEMs have good perspectives for high temperature proton exchange membrane fuel cell applications.

机译：在这项研究中，成功地合成并表征了磷酸掺杂的疏水离子液体基复合膜。合成了1-乙烯基-3-丁基咪唑鎓双（三氟甲基磺酰基）-酰亚胺（[VBIm] [NTf _{2 ]），并在复合膜中用作疏水相。复合膜的H _{3 PO _{4 吸收随着[VBIm] [NTf < small> _{2 ]，然后减小。所得复合膜表现出良好的热稳定性，机械性能和高质子传导性（高达10 ？2 S cm ？1 （在180°C下）在无水条件下的高温下。这项研究的结果表明，这种类型的PEM对高温质子交换膜燃料电池的应用具有良好的前景。}}}}

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《RSC Advances》 |2017年第2期|共6页
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Bencai Lin; Gang Qiao; Fuqiang Chu; Shuai Zhang; Ningyi Yuan; Jianning Ding;
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1. Phosphoric acid doped hydrophobic ionic liquid-based composite membranes for anhydrous proton exchange membrane application [J] . Bencai Lin, Gang Qiao, Fuqiang Chu, RSC Advances . 2017,第2期

机译：磷酸掺杂疏水离子液体基复合膜在无水质子交换膜中的应用
2. Phosphoric acid doped polybenzimidazole/imidazolium-modified silsesquioxane hybrid proton conducting membranes for anhydrous proton exchange membrane application [J] . Bencai Lin, Fuqiang Chu, Ningyi Yuan, Journal of power sources . 2014,第apra15期

机译：磷酸掺杂的聚苯并咪唑/咪唑改性的倍半硅氧烷杂化质子传导膜，用于无水质子交换膜的应用
3. Macromolecular protic ionic liquid-based proton-conducting membranes for anhydrous proton exchange membrane application [J] . Fuqiang Chu, Bencai Lin, Feng Yan, Journal of power sources . 2011,第19期

机译：用于无水质子交换膜的高分子质子离子液体基质子传导膜
4. High temperature proton exchange membranes based on various heteropoly acids (HPW, HSiW, HPMo or HSiMo) functionalized silica nanocomposites with tunable mesoporous structure and superior proton conductivity for fuel cells [C] . J. Zeng, S. P. Jiang, L. Li Polymer Electrolyte Fuel Cells 11 . 2013

机译：基于多种杂多酸（HPW，HSiW，HPMo或HSiMo）的功能化二氧化硅纳米复合材料的高温质子交换膜，具有可调的介孔结构和优异的质子传导性，可用于燃料电池
5. Molecular Simulation of Phosphoric Acid-Doped Polybenzimidazoles as High- Temperature Proton Exchange Membranes. [D] . Li, Shuo. 2011

机译：磷酸掺杂的聚苯并咪唑作为高温质子交换膜的分子模拟。
6. Synthesis and Properties of Phosphoric-Acid-Doped Polybenzimidazole with Hyperbranched Cross-Linkers Decorated with Imidazolium Groups as High-Temperature Proton Exchange Membranes [O] . Chunmei Gao, Meishao Hu, Li Wang, 2020

机译：咪唑鎓基团修饰的超支化交联剂磷酸掺杂的聚苯并咪唑的合成及性能
7. Phosphoric acid doped hydrophobic ionic liquid-based composite membranes for anhydrous proton exchange membrane application [O] . Bencai Lin, Gang Qiao, Fuqiang Chu, 2017

机译：用于无水质子交换膜应用的磷酸掺杂疏水离子液体复合膜

Phosphoric acid doped hydrophobic ionic liquid-based composite membranes for anhydrous proton exchange membrane application

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