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Facile fabrication of polyaniline@γ-MnOOH on a buckypaper ternary composite electrode for free-standing supercapacitors

机译:在独立式超级电容器的巴克纸三元复合电极上轻松制备聚苯胺@γ-MnOOH

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Ternary composites as electrode materials have attracted extensive attention due to their excellent electrochemical performance in energy-storage technologies as compared to single or binary composites. Herein, we demonstrated a facile two-step method to construct a new hierarchical nanocomposite by combing buckypaper (BP) with γ-MnOOH nanorods and polyaniline. BP is used as a conductive substrate for the synthesis of free-standing hierarchical electrodes. The structural characterizations revealed the growth of a hierarchical porous structure of the ternary electrode. The synthesized polyaniline@γ-MnOOH–BP ternary composite electrode shows a maximum specific capacitance of 567.5 F g?1 at a current density of 0.5 A g?1 and a relatively high areal capacitance of 301.2 mF cm?2 at a current density of 0.27 mA cm?2. This intriguing result is ascribed to the good combination of BP, γ-MnOOH, and PANI. We believe that this ternary composite electrode has potential in portable, environmentally friendly, and wearable applications for next generation energy-storage devices.
机译:作为电极材料的三元复合材料,由于其在储能技术中的电化学性能优于单一或二元复合材料,因此引起了广泛的关注。在本文中,我们展示了一种简便的两步法,通过将布基纸(BP)与γ-MnOOH纳米棒和聚苯胺相结合来构建新的分层纳米复合材料。 BP用作合成独立式分层电极的导电基底。结构表征显示三元电极的分层多孔结构的生长。合成的聚苯胺@γ-MnOOH-BP三元复合电极在电流密度为0.5 A g ?1 >?1 和相对较高的面电容301.2 mF cm ?2 ,电流密度为0.27 mA cm ?2 。这个有趣的结果归因于BP,γ-MnOOH和PANI的良好结合。我们相信,这种三元复合电极在下一代储能设备的便携式,环保和可穿戴应用中具有潜力。

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