Selective aerobic benzylic C–H oxidation co-catalyzed by N-hydroxyphthalimide and Keplerate {Mo72V30} nanocluster

Abdolreza Rezaeifard; Ashkan Khoshyan; Maasoumeh Jafarpour; Mehrdad Pourtahmasb

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Selective aerobic benzylic C–H oxidation co-catalyzed by N-hydroxyphthalimide and Keplerate {Mo₇₂V₃₀} nanocluster

机译： N -羟基邻苯二甲酰亚胺和Keplerate {Mo _{72 V _{30 }纳米簇共催化的选择性好氧苄基CH氧化}}

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The catalytic efficiency of a Keplerate {Mo₇₂V₃₀} nanocapsule in the aerobic benzylic C–H oxidation of alcohols and hydrocarbons was exploited. The aerobic reactions were conducted using catalytic amounts of {Mo₇₂V₃₀} and under the co-catalytic effects of NHPI (N-hydroxyphthalimide) to furnish desired aldehydes and ketones in high yields and excellent selectivity. Different benzylic alcohols and hydrocarbons were shown to be amenable to oxidation under standard conditions presented here. Spectral data and leaching experiments revealed that the cluster had a long-term stability and could be used repeatedly in consecutive runs. 展开▼

机译：Keplerate {Mo _{72 V _{30 }纳米胶囊在好氧苄基C–H氧化中的催化效率酒精和碳氢化合物得到了利用。在有助催化作用的条件下，利用{Mo _{72 V _{30 }催化量进行好氧反应。 NHPI（ N -羟基邻苯二甲酰亚胺）能够以高收率和优异的选择性提供所需的醛和酮。在这里介绍的标准条件下，显示出不同的苄醇和烃类易于氧化。光谱数据和浸出实验表明该团簇具有长期稳定性，可以在连续运行中重复使用。}}}} 展开▼

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《RSC Advances》 |2017年第26期|共8页

作者
Abdolreza Rezaeifard; Ashkan Khoshyan; Maasoumeh Jafarpour; Mehrdad Pourtahmasb;
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中图分类化学;

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专利

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机译：有氧{mo72v30}纳米群催化的异质一罐苯并咪唑串联合成

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机译：高温下水溶液中巨大的{Mo_（72）Fe_（30）}型多金属氧酸盐团簇的命运：了解从分子到材料的相关酮戊酸酯化学

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机译：PEG-1000O型阳离子液体对N-羟基邻苯二甲酰亚胺催化的烷基链烷烃有氧选择性氧化的显著作用

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机译：N-羟基邻苯二甲酰亚胺介导的无金属需氧氧化。简洁的评论

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机译：选择性甲烷氧化促进氧化物催化剂。季度报告，1995年9月1日至11月30日

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2. Vishay推出业界最薄的新型20V P通道TrenchFET功率MOSFET [J] . 章从福 . 半导体信息 . 2008,第004期

3. Catalyst半导体发布超低功耗8位IC/SMBus总线I/O扩展器/Vishay推出新型20V P通道TrenchFET功率MOSFET [J] . . 电子与电脑 . 2008,第007期

4. Expression of CC Chemokine Ligand 20 and CC Chemokine Receptor 6 mRNA in Patients with Psoriasis Vulgaris [J] . 吴艳 ,李家文 . 华中科技大学学报（医学）（英德文版） . 2004,第003期

5. 铝-氟-邻羟基苯芴酮-吐温-20多元反应体系用于光度法测定痕量铝 [J] . 张龙庄 ,卫文红 ,梅菊 . 理化检验-化学分册 . 2010,第006期

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2. 3-羟基-孕甾-21-(2′,5′-二甲氧基)苯亚甲基-5-烯-20-酮、其制备方法和用途 [P] . 中国专利： CN102850424B . 2015.12.09

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机译：通过在0到30之间的温度进行本体聚合可以看到吗？分子量降低的72°C弗氏杆菌氯乙烯聚合物

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机译：不含氧化硅的锌硼酸铅玻璃，折射率介于1,72至1,81之间，介于30至45之间

5. Silicon oxide free zinc - lead - borate glass with high refractive indices of 1,72 to 1,81 down and the middle between numbers of from 30 to 45 [P] . 外国专利： DE1596990B2 . 1972-11-02

机译：不含氧化硅的锌硼酸铅玻璃，折射率介于1,72至1,81之间，介于30至45之间

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Selective aerobic benzylic C–H oxidation co-catalyzed by N-hydroxyphthalimide and Keplerate {Mo72V30} nanocluster

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Selective aerobic benzylic C–H oxidation co-catalyzed by N-hydroxyphthalimide and Keplerate {Mo₇₂V₃₀} nanocluster