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Interface tailoring through the supply of optimized oxygen and hydrogen to semiconductors for highly stable top-gate-structured high-mobility oxide thin-film transistors

机译:通过向半导体提供优化的氧气和氢气来进行界面定制,以实现高度稳定的顶栅结构高迁移率氧化物薄膜晶体管

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Self-aligned structured oxide thin-film transistors (TFTs) are appropriate candidates for use in the backplanes of high-end displays. Although SiN _( x ) is an appropriate candidate for use in the gate insulators (GIs) of high-performance driving TFTs, direct deposition of SiN _( x ) on top of high-mobility oxide semiconductors is impossible due to significant hydrogen (H) incorporation. In this study, we used AlO _( x ) deposited by thermal atomic layer deposition (T-ALD) as the first GI, as it has good H barrier characteristics. During the T-ALD, however, a small amount of H from H _(2) O can also be incorporated into the adjacent active layer. In here, we performed O _(2) or N _(2) O plasma treatment just prior to the T-ALD process to control the carrier density, and utilized H to passivate the defects rather than generate free carriers. While the TFT fabricated without plasma treatment exhibited conductive characteristics, both O _(2) and N _(2) O plasma-treated TFTs exhibited good transfer characteristics, with a V _(th) of 2 V and high mobility (~30 cm ~(2) V ~(?1) s ~(?1) ). Although the TFT with a plasma-enhanced atomic layer deposited (PE-ALD) GI exhibited reasonable on/off characteristics, even without any plasma treatment, it exhibited poor stability. In contrast, the O _(2) plasma-treated TFT with T-ALD GI exhibited outstanding stability, i.e. , a V _(th) shift of 0.23 V under positive-bias temperature stress for 10 ks and a current decay of 1.2% under current stress for 3 ks. Therefore, the T-ALD process for GI deposition can be adopted to yield high-mobility, high-stability top-gate-structured oxide TFTs under O _(2) or N _(2) O plasma treatment.
机译:自对准结构化氧化物薄膜晶体管(TFT)是适合用于高端显示器背板的候选材料。尽管SiN _(x)是适合用于高性能驱动TFT的栅极绝缘体(GI)的候选材料,但是由于存在大量的氢(H),因此无法在高迁移率氧化物半导体的顶部直接沉积SiN _(x)。 )成立。在这项研究中,我们使用通过热原子层沉积(T-ALD)沉积的AlO _(x)作为第一个GI,因为它具有良好的H势垒特性。然而,在T-ALD期间,也可以将来自H_(2)O的少量H引入到相邻的有源层中。在这里,我们在T-ALD工艺之前进行O_(2)或N_(2)O等离子体处理,以控制载流子密度,并利用H钝化缺陷而不产生自由载流子。尽管未经等离子体处理的TFT表现出导电特性,但O _(2)和N _(2)O等离子体处理的TFT都表现出良好的转移特性,V _(th)为2 V,迁移率高(约30 cm) 〜(2)V〜(?1)s〜(?1))。尽管具有等离子体增强的原子层沉积(PE-ALD)GI的TFT表现出合理的开/关特性,但即使不进行任何等离子体处理,其稳定性也很差。相比之下,具有T-ALD GI的O _(2)等离子体处理的TFT表现出出色的稳定性,即在10 ks的正偏置温度应力下V_(th)的偏移为0.23 V,电流衰减为1.2%在3 ks的电流应力下。因此,可以采用用于GI沉积的T-ALD工艺在O _(2)或N _(2)O等离子体处理下产生高迁移率,高稳定性的顶栅结构氧化物TFT。

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