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Facile transformation of low cost melamine–oxalic acid into porous graphitic carbon nitride nanosheets with high visible-light photocatalytic performance

机译:低成本三聚氰胺-草酸轻松转化为具有高可见光光催化性能的多孔石墨氮化碳纳米片

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Here, we report a simple, robust and large-quantity synthetic pathway to form porous graphitic carbon nitride nanosheet structures, using a long strip-like structure of melamine–oxalic acid (MO) as a starting product. The addition of oxalic acid can influence the thermal condensation model and inhibit grain growth of g-C3N4. Meanwhile, the synergism of MO precursor and specific heating process can effectively adjust the porosity and number of layers. The synthesized porous g-C3N4 nanosheets possess large specific surface areas (203 m2 g?1), a widened band gap 2.98 eV, and improved electron transport ability, exhibit high photocatalytic activities as much as 8 times than bulk g-C3N4 for the photodegradation of gas pollute under visible light (λ > 420 nm). This work shows a significant progress for low-cost fabrication of high quality porous 2D g-C3N4 with excellence photocatalytic activity.
机译:在这里,我们报道了一种简单,稳健且数量众多的合成途径,以长条状的三聚氰胺-草酸(MO)形式形成多孔石墨碳氮化碳纳米片结构。草酸的添加会影响g-C 3 N 4 的热缩合模型并抑制其晶粒长大。同时,MO前驱体与特定加热工艺的协同作用可以有效地调节孔隙率和层数。合成的多孔gC 3 N 4 纳米片具有较大的比表面积(203 m 2 g ?1 ),带隙宽2.98 eV,电子传输能力提高,具有高达8倍的高光催化活性。比块状gC 3 N 4 在可见光(λ 3 N 4 的重大进展光催化活性。

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