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Underwater superoleophobic polyurethane-coated mesh with excellent stability for oil/water separation

机译:水下超疏油聚氨酯涂层筛网,具有出色的油/水分离稳定性

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Oil/water separation has been a challenge in chemical engineering for various applications. There are numbers of studies on using coated metal meshes as a filter for oil/water separation. However, water resistance, chemical (such as: acid, base, and fouling) resistance and heat resistance for coating materials need further exploration, especially in terms of the durability of the coating materials. In this study, we synthesized a new coating material, hydrophilic polycarbonate polyurethane (HPCPU). We used HPCPU to chemically modify a steel mesh, and the mesh exhibits superhydrophilic and underwater superoleophobic properties. The HPCPU coated mesh shows excellent capacity for oil/water separation with a separation efficiency higher than 99.99% even after 40 cycles of separation. The coating material also exhibits excellent properties of water resistance, heat resistance, and chemical resistance. Moreover, the HPCPU-coated mesh exhibits a strong durability. For example, the separation efficiency for various oil/water mixtures remains higher than 99.7% after the HPCPU-coated mesh has been soaked in water for 30 days, hot water for 5 days, oils for 5 days, 0.5?M HCl solution, 0.5 M NaOH solution and 0.5 M NaCl solution for 24 hours.
机译:油水分离一直是化学工程在各种应用中的挑战。关于使用涂层金属网作为油/水分离过滤器的研究很多。但是,涂料的耐水性,化学(例如,酸,碱和污垢)和耐热性需要进一步研究,特别是在涂料的耐久性方面。在这项研究中,我们合成了一种新型涂料,亲水性聚碳酸酯聚氨酯(HPCPU)。我们使用HPCPU对钢网进行化学改性,并且该网具有超亲水性和水下超疏油性。带有HPCPU涂层的筛网具有出色的油/水分离能力,即使经过40次分离,其分离效率仍高于99.99%。该涂料还显示出优异的耐水性,耐热性和耐化学性。而且,涂有HPCPU的网格具有很强的耐久性。例如,将涂有HPCPU的筛网在水中浸泡30天,在热水中浸泡5天,在油中浸泡5天,0.5?M HCl溶液,0.5浸泡后,各种油/水混合物的分离效率仍高于99.7%。 M NaOH溶液和0.5 M NaCl溶液24小时。

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