• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>RSC Advances >Green-solvent-processed hybrid solar cells based on donor–acceptor conjugated polyelectrolyte
【24h】

Green-solvent-processed hybrid solar cells based on donor–acceptor conjugated polyelectrolyte

机译：基于供体-受体共轭聚电解质的绿色溶剂处理混合太阳能电池

获取原文
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

In this work, a quaternary ammonium side chain modified conjugated polyelectrolyte PFBTBr, with excellent solubility in nonaromatic and nonhalogenated solvents, was designed and synthesized as the donor material for the green-solvent-processed hybrid solar cells (HSCs). By introducing the donor–acceptor structure, PFBTBr shows a lower lying highest occupied molecular orbital (HOMO) level and a broad absorption from 300 to 700 nm. Incorporating the water soluble CdTe nanocrystals (NCs) as acceptor, the green-solvent-processed HSCs based on conjugated polyelectrolyte and inorganic NCs were fabricated. Through the active layer optimization, a well blended donor/acceptor active layer with continuous electron/hole transport pathway and smoother surface was achieved. As a result, a photovoltaic efficiency of 3.67% was realized. After the further interfacial modification and chloride treatment, the power conversion efficiency of the green-solvent-processed HSCs was improved to 5.03% with the maximum external quantum efficiency value of 87.01% at 400 nm under the AM 1.5 G 100 mW cm ~(?2) illumination.
机译：在这项工作中，设计并合成了季铵侧链改性的共轭聚电解质PFBTBr，在非芳香族和非卤代溶剂中具有优异的溶解性，作为绿色溶剂处理的混合太阳能电池（HSC）的供体材料。通过引入施主-受主结构，PFBTBr显示出较低的最高占据分子轨道（HOMO）水平和300至700 nm的宽吸收。结合水溶性CdTe纳米晶体（NCs）作为受体，制备了基于共轭聚电解质和无机NCs的绿色溶剂处理的HSC。通过优化活性层，可以实现具有连续电子/空穴传输路径和光滑表面的良好混合的供体/受体活性层。结果，实现了3.67％的光伏效率。经过进一步的界面改性和氯化处理后，在AM 1.5 G 100 mW cm〜（？）下，经绿色溶剂处理的HSC的功率转换效率提高至5.03％，在400 nm处的最大外部量子效率值为87.01％。 2）照明。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号