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Enhanced thermoelectric properties of In2O3(ZnO)5 intrinsic superlattice ceramics by optimizing the sintering process

机译:通过优化烧结工艺增强了In 2 O 3 (ZnO) 5 本征超晶格陶瓷的热电性能

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Thermoelectric (TE) materials have a promising application as they can interconvert thermal energy to electrical energy directly. Oxide TE materials have attracted more attention for this application due to their high temperature stability. In this work, In2O3(ZnO)5 intrinsic superlattice ceramics with a layered structure were synthesized by reaction sintering a mixed powder of In2O3 and ZnO at 1200?°C for different holding times (t = 6, 8, 10, 12 and 15 h) in air. Their thermoelectric properties including the electrical conductivity, Seebeck coefficient and thermal conductivity, were measured from 323 to 973 K. The thermoelectric properties depended on the holding time. The highest ZT value of 0.19 at 973 K was obtained for the sample with a 12 h holding time.
机译:热电(TE)材料具有广阔的应用前景,因为它们可以将热能直接互转换为电能。氧化物TE材料由于其高温稳定性而吸引了更多关注。在这项工作中,In 2 O 3 (ZnO) 5 通过对In 2 O 3 的混合粉末进行反应烧结,合成出具有层状结构的本征超晶格陶瓷。和ZnO在1200?C下在空气中的不同保持时间( t = 6、8、10、12和15 h)。在323至973 K范围内测量了它们的热电性能,包括电导率,塞贝克系数和热导率。热电性能取决于保持时间。保持时间为12 h的样品在973 K下获得的最高 ZT 值为0.19。

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