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Synthesis and application of monodisperse hydrophobic magnetite nanoparticles as an oil spill collector using an ionic liquid

机译:使用离子液体的疏水性磁铁矿单分散纳米颗粒的合成及应用

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In this work, a new facile green method was proposed to prepare monodisperse magnetic nanoparticles at room temperature with controlled shape and size. In this respect, a new ionic liquid based on 1-allyl-3-methylimidazolium oleate (AMO) was prepared and applied as a capping and stabilizing agent for magnetite at low temperature. The chemical structure, morphology, particle size, crystal structure and monodispersity of magnetite capped with AMO were determined. The magnetic properties and porosity of the prepared magnetite nanomaterials were evaluated using different analytical techniques. The efficiency of the prepared magnetite nanomaterials as an oil spill collector confirmed their high selectivity and oil collection efficiency on the surface of seawater using a low concentration of nanomaterials in relation to the size of the crude oil spill.
机译:在这项工作中,提出了一种新的简便绿色方法,以在室温下以受控的形状和尺寸制备单分散磁性纳米粒子。在这方面,制备了基于油酸1-烯丙基-3-甲基咪唑鎓(AMO)的新型离子液体,并将其用作低温磁铁矿的封端和稳定剂。测定了AMO包覆的磁铁矿的化学结构,形貌,粒径,晶体结构和单分散性。使用不同的分析技术评估了制备的磁铁矿纳米材料的磁性能和孔隙率。所制备的磁铁矿纳米材料作为溢油收集器的效率证实了使用相对于原油溢油大小的低浓度的纳米材料,其在海水表面的高选择性和集油效率。

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