Bi<sub>2</sub>O<sub>3</sub> modification of HZSM-5 for methanol-to-propylene conversion: evidence of olefin-based cycle

Hairong Zhang; Zhangxuan Ning; Hongyan Liu; Jianpeng Shang; Shenghua Han; Dingding Jiang; Yu Jiang; Yong Guo

首页> 外文期刊>RSC Advances >Bi₂O₃ modification of HZSM-5 for methanol-to-propylene conversion: evidence of olefin-based cycle

【24h】

Bi₂O₃ modification of HZSM-5 for methanol-to-propylene conversion: evidence of olefin-based cycle

机译：HZSM-5的Bi _{2 O _{3 修饰用于甲醇转化为丙烯：基于烯烃的循环的证据}}

获取原文

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Bi₂O₃-modified HZSM-5 catalysts were prepared via a traditional wetness impregnation approach, and used for the methanol-to-propylene conversion reaction. The selectivity for propylene increases significantly with bismuth loading, while that for ethylene shows the opposite trend. However, the Bi₂O₃/HZSM-5 catalysts have significantly lower capacities for methanol conversion than the parent HZSM-5. The underlying causes are the reduced acid site strength, narrower pore openings, and reduced pore width in Bi₂O₃/HZSM-5. This work provides insights into the olefin-based cycle operation for methanol-to-olefin reactions using modified HZSM-5 catalysts.

机译：通过传统的方法制备了Bi _{2 O _{3 改性的HZSM-5催化剂。湿法浸渍法，并用于甲醇向丙烯的转化反应。丙烯的选择性随铋的负载而显着增加，而乙烯的选择性则呈现相反的趋势。但是，Bi _{2 O _{3 / HZSM-5催化剂的甲醇转化能力明显低于母体HZSM-5。根本原因是Bi _{2 O _{3 / HZSM-5。这项工作为使用改性的HZSM-5催化剂的甲醇制烯烃反应中基于烯烃的循环操作提供了见识。}}}}}}

著录项

来源
《RSC Advances》 |2017年第27期|共6页
作者
Hairong Zhang; Zhangxuan Ning; Hongyan Liu; Jianpeng Shang; Shenghua Han; Dingding Jiang; Yu Jiang; Yong Guo;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. Catalytic Study of Methanol-to-Propylene Conversion over Nano-Sized HZSM-5 [J] . Jianwen Li, Hongfang Ma, Weixin Qian, International Journal of Information Technology . 2018,第4期

机译：HZSM-5纳米催化剂催化甲醇制丙烯转化反应的研究
2. A descriptor for the relative propagation of the aromatic- and olefin-based cycles in methanol-to-hydrocarbons conversion on H-ZSM-5 [J] . Ilias S., Khare R., Malek A., Journal of Catalysis . 2013,第Null期

机译：H-ZSM-5上甲醇到烃类转化中芳烃和烯烃基循环的相对传播的描述子
3. Methanol-to-Olefin Conversion over Small-Pore DDR Zeolites: Tuning the Propylene Selectivity via the Olefin-Based Catalytic Cycle [J] . Hua Jia, Dong Xinglong, Wang Jianjian, ACS catalysis . 2020,第5期

机译：甲醇 - 烯烃在小孔径DDR沸石上转化：通过基于烯烃的催化循环调节丙烯选择性
4. Effect of Zr modification to Cu-ZnO-Al2O3/HZSM-5 on catalytic performance for direct synthesis of dimethyl ether from biomass-derived syngas [C] . Faen Song, Yisheng Tan, Hongjuan Xie ACS National Meeting and Exhibition . 2013

机译：Zr改性对Cu-ZnO-Al2O3 / HZSM-5对生物量衍生合成气直接合成二甲醚的催化性能的影响
5. Olefin-based polymer synthesis and modification via transition metal catalysis [D] . Murtuza, Shahid Mateen 1999

机译：过渡金属催化的烯烃基聚合物合成和改性
6. Smart Modification of HZSM-5 with ManganeseSpecies for the Removal of Mercury [O] . Haining Wang, Wei Ma, Jiangbo Yan, 2020

机译：HZSM-5与锰的智能改性用于去除汞的物种
7. Bi2O3 modification of HZSM-5 for methanol-to-propylene conversion: evidence of olefin-based cycle [O] . Hairong Zhang, Zhangxuan Ning, Hongyan Liu, 2017

机译：Bi2O3改性HZSM-5用于甲醇 - 丙烯转化：基于烯烃的循环的证据

Bi2O3 modification of HZSM-5 for methanol-to-propylene conversion: evidence of olefin-based cycle

摘要

著录项

相似文献

相关主题

期刊订阅

Bi₂O₃ modification of HZSM-5 for methanol-to-propylene conversion: evidence of olefin-based cycle