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Ethanol sensor development based on ternary-doped metal oxides (CdO/ZnO/Yb2O3) nanosheets for environmental safety

机译:基于三元掺杂金属氧化物(CdO / ZnO / Yb 2 O 3 )纳米片的乙醇传感器开发对环境安全的影响

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Herein, we report the construction of a dynamic, highly sensitive, stable, reliable, and reproducible selective ethanol sensor based on a ternary metal oxide system of CdO/ZnO/Yb2O3 nanosheets (NSs). The NSs were synthesized by a hydrothermal process in alkaline phases. The morphological and structural characterization of the synthesized NSs were approved using various advantageous and well-established conventional methods such as Fourier-transform infrared spectroscopy (FTIR), ultraviolet visible spectroscopy (UV/vis), field emission scanning electron microscopy (FESEM), X-ray photoelectron spectroscopy (XPS), energy-dispersive X-ray spectroscopy (EDS), and powder X-ray diffraction (XRD). A thin layer of CdO/ZnO/Yb2O3 NSs was deposited onto a glassy carbon electrode (GCE) with conducting binder to produce a working electrode. A calibration plot was obtained and was found to be linear over the ethanol concentration range (linear dynamic range, LDR) from 0.35 nM to 3.5 mM with the detection limit (LoD) of 0.127 ± 0.006 nM and the quantification limit (LoQ) of 0.423 ± 0.02 (signal-to-noise ratio, at the S/N of 3), and the system exhibited a sensitivity of 7.4367 μA mM?1 cm?2. Furthermore, the proposed chemical sensor was successively applied for the detection of ethanol in various environmental samples. This approach was introduced as a well-organized route for efficient ethanol sensor development in environmental and health-care fields in a broad scale.
机译:在此,我们报告了基于CdO / ZnO / Yb 2 三元金属氧化物系统的动态,高灵敏,稳定,可靠且可重现的选择性乙醇传感器的构建O 3 纳米片(NSs)。通过水热过程在碱性相中合成NS。合成的NSs的形态和结构特征已通过各种有利的和公认的常规方法得到批准,例如傅立叶变换红外光谱(FTIR),紫外可见光谱(UV / vis),场发射扫描电子显微镜(FESEM),X射线光电子能谱(XPS),能量色散X射线能谱(EDS)和粉末X射线衍射(XRD)。将CdO / ZnO / Yb 2 O 3 NSs薄层沉积在玻璃碳电极上(GCE )与导电粘合剂,以产生工作电极。获得了一个校准图,发现该图在乙醇浓度范围(线性动态范围,LDR)(从0.35 nM到3.5 mM)中呈线性,检测极限(LoD)为0.127±0.006 nM,定量极限(LoQ)为0.423 ±0.02(信噪比,S / N为3),系统显示的灵敏度为7.4367μAmM ?1 cm < sup>?2 。此外,所提出的化学传感器被相继应用于各种环境样品中乙醇的检测。这种方法是为在环境和医疗保健领域进行大规模有效乙醇传感器开发而精心组织的方法。

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