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Enhanced thermoelectric performance in n-type polycrystalline SnSe by PbBr2 doping

机译:PbBr 2 掺杂增强n型多晶SnSe的热电性能

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A series of PbBr2-doped polycrystalline SnSe samples were synthesized by melting and hot pressing. By PbBr2 doping, the carrier concentration of SnSe was increased to 1.86 × 1019 cm?3 from 2.41 × 1017 cm?3, resulting in an increased electrical conductivity of 40 ± 2 S cm?1 at 713 K while the undoped SnSe was only 5.1 ± 0.3 S cm?1. Meanwhile, the PbBr2-doped samples also exhibit a larger density of state effective mass (0.812m0). Therefore, a high power factor of 4.8 ± 0.5 μW cm?1 K?2 and a peak ZT of 0.54 ± 0.1 were achieved at 793 K perpendicular to the hot pressing direction.
机译:通过熔融和热压合成了一系列掺杂PbBr 2 的多晶SnSe样品。通过掺杂PbBr 2 ,SnSe的载流子浓度增加到1.86×10 19 cm < sup>?3 从2.41×10 17 cm ?3 在713 K下电导率增加40±2 S cm ?1 ,而未掺杂的SnSe仅为5.1±0.3 S cm ?1 < / sup> 。同时,掺杂PbBr 2 的样品也表现出较大的状态有效质量密度(0.812 m 0 )。因此,高功率因数为4.8±0.5μWcm ?1 K ?2 ,峰值为 ZT 为0.54±0.1。

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