首页> 外文期刊>RSC Advances >A low molecular mass organogelator electrolyte with TiO2 nanoparticles for stable and efficient quasi-solid-state dye sensitized solar cells
【24h】

A low molecular mass organogelator electrolyte with TiO2 nanoparticles for stable and efficient quasi-solid-state dye sensitized solar cells

机译:具有TiO 2 纳米粒子的低分子量有机胶凝剂电解质,用于稳定高效的准固态染料敏化太阳能电池

获取原文
           

摘要

We report stable and efficient quasi-solid-state dye-sensitized solar cells (QS-DSSCs) fabricated using a combination of TiO2 nanoparticles and a low-molecular-mass organogelator (LMOG) as a nanoparticle–gel composite electrolyte. Three types of electrolyte, namely liquid, LMOG-based gel, and nanoparticle–gel composite, are used. The results of electrochemical impedance spectroscopy and intensity-modulated photocurrent/photovoltage spectroscopy measurements suggest that the presence of TiO2 nanoparticles in the nanoparticle–gel composite electrolyte could afford faster electron transport and a longer electron recombination time compared to the liquid and LMOG-based gel electrolytes. The QS-DSSC using the nanoparticle–gel composite electrolyte with the optimal TiO2 content exhibits a power conversion efficiency of 7.79%, which is significantly higher than that of devices using the liquid (7.22%) and LMOG-based gel (7.21%) electrolytes. Remarkably, the QS-DSSCs with the optimal nanoparticle–gel composite electrolyte exhibit long-term stability over 10 days, unlike the liquid electrolyte-based cells.
机译:我们报告稳定和有效的准固态染料敏化太阳能电池(QS-DSSCs)使用TiO 2 纳米粒子和低分子质量有机胶凝剂的组合制造(LMOG)作为纳米凝胶复合电解质。使用三种类型的电解质,即液体电解质,基于LMOG的凝胶和纳米颗粒-凝胶复合材料。电化学阻抗谱和强度调制的光电流/光电压谱的测量结果表明,纳米粒子-凝胶复合电解质中存在TiO 2 纳米粒子可以提供更快的电子传输和与液体和基于LMOG的凝胶电解质相比,具有更长的电子复合时间。使用具有最佳TiO 2 含量的纳米粒子-凝胶复合电解质的QS-DSSC的功率转换效率为7.79%,这明显高于使用该材料的器件的功率转换效率。液体(7.22%)和基于LMOG的凝胶(7.21%)电解质。值得注意的是,与基于液体电解质的电池不同,具有最佳纳米颗粒-凝胶复合电解质的QS-DSSCs在10天内显示出长期稳定性。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号