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Green solid-state synthesis and photocatalytic hydrogen production activity of anatase TiO2 nanoplates with super heat-stability

机译:超高热稳定性锐钛矿型TiO 2 纳米板的绿色固态合成及光催化制氢活性

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A simple and environmentally friendly new method, a low-heating solid-state chemical method (LSCM), has been used to prepare uniform NH4TiOF3 nanoplates with a thickness of about 100 nm in the absence of surfactants. The solid–solid transformation was used to convert NH4TiOF3 nanoplates to TiO2 nanoplates with an exposed (001) facet via a simple sintering process at different temperatures. The anatase TiO2 nanoplates obtained in this work have super heat-stability, and can withstand high temperatures and maintain highly active anatase up to 1000 °C. The obtained compact TiO2 nanoplates have high photocurrent density and photocatalytic hydrogen-production activity, better than as-prepared TiO2 porous nanoplates and reported values in the literature, which is due to the exposed (001) facet and the high degree of crystallinity. This work provides a simple, efficient and environmentally friendly way to prepare TiO2 nanoplates and nanoparticles, and also offers a new approach for preparing anatase TiO2 with super heat-stability and high reactivity, which can be applied to H2-production via photocatalytic water splitting.
机译:一种简单且环保的新方法,即低热固态化学方法(LSCM),已用于制备均匀的NH 4 TiOF 在没有表面活性剂的情况下,厚度约为100 nm的3 纳米板。固-固转化用于将NH 4 TiOF 3 纳米板转化为TiO 通过简单的烧结过程在不同温度下暴露2个 纳米板()。这项工作中获得的锐钛矿型TiO 2 纳米板具有极高的热稳定性,可以承受高温并保持高达1000°C的高活性锐钛矿。所得致密TiO 2 纳米板具有较高的光电流密度和光催化制氢活性,优于制备的TiO 2 小>多孔纳米板和文献报道的值,这是由于暴露的(001)小平面和高度的结晶度。这项工作为制备TiO 2 纳米板和纳米颗粒提供了一种简单,高效,环保的方法,也为制备锐钛矿型TiO 2的新方法提供了一种新方法。 具有超高的热稳定性和高反应活性,可用于通过光催化水生产H 2 分裂。

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