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Li2ZnTi3O8/graphene nanocomposite as a high-performance anode material for lithium-ion batteries

机译:Li2ZnTi3O8 /石墨烯纳米复合材料作为锂离子电池的高性能负极材料

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An Li _(2) ZnTi _(3) O _(8) /graphene (LZTO/G) anode is successfully synthesized by a two-step reaction. The results show that LZTO particles can be well dispersed into the graphene conductive network. The conductive structure greatly improves the electrochemical performance of LZTO/G. When cycled for 400 cycles, 76.4% of the capacity for the 2nd cycle is maintained at 1 A g ~(?1) . Also, 174.8 and 156.5 mA h g ~(?1) are still delivered at the 100th cycle for 5 and 6 A g ~(?1) , respectively. The excellent cyclic performance and the large specific capacities at high current densities are due to the good conductive network of the LZTO active particles, large pore volume, small particle size, low charge-transfer resistance and high lithium diffusion coefficient.
机译:通过两步反应成功合成了Li _(2)ZnTi _(3)O _(8)/石墨烯(LZTO / G)阳极。结果表明,LZTO颗粒可以很好地分散到石墨烯的导电网络中。导电结构大大提高了LZTO / G的电化学性能。当循环400个循环时,第二个循环的容量的76.4%保持在1 A g〜(?1)。同样,在第100个周期仍分别提供54.8和6 A g〜(?1)的174.8 mA h g〜(?1)。优异的循环性能和高电流密度下的大比容量归因于LZTO活性颗粒的良好导电网络,大孔体积,小粒径,低电荷转移电阻和高锂扩散系数。

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